rubidium cobalt(III) hexacyanoferrate(III) | 433259-52-0

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: rubidium cobalt(III) hexacyanoferrate(III)
• CAS: 433259-52-0
• 化学式: C₆FeN₆*Co*Rb
• 分子量: 356.414
• InChiKey: QAGACQIXYRFGMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  rubidium nitrate 、 cobalt(II) nitrate 、 potassium hexacyanoferrate(III) 以 水 为溶剂， 生成 rubidium cobalt(III) hexacyanoferrate(III)
  参考文献：
  名称：

  Cobalt Hexacyanoferrate:  Compound Stoichiometry, Infrared Spectroelectrochemistry, and Photoinduced Electron Transfer

  摘要：

  The cobalt hexacyanoferrate, MhCokA[Fe-B(CN)(6)](t), (where M is an alkali metal cation, and the subscripts h, k, and l are stoichiometric coefficients, and A and B are the formal oxidation states of the Co and Fe metal sites in the structure) was shown to contain a rich series of compounds that are inter-linked through various redox processes (involving both electron and cation transfer) either in the dark or under the near-infrared (IR) activation. These processes were studied by a combined use of cyclic voltammetry, in situ IR spectroelectrochemistry (using both intensity or potential modulation), and ex situ X-ray photoelectron spectroscopy.

  DOI：

  10.1021/jp013991r