| 1600523-84-9

• CAS: 1600523-84-9
• 化学式: C₄₄H₃₈ClNOP₂Ru
• 分子量: 795.262
• InChiKey: SAJAOFCBTDIFOW-XZKKPRKESA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 thallous salt of N-methylsalicylaldimine 以 四氢呋喃 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Catalytic activity and selectivity of a range of ruthenium complexes tested in the styrene/EDA reaction system

  摘要：

  The complex ensemble of competing chemical processes (cyclopropanation, metathesis, dimerisation) involved in the reaction of ethyl diazoacetate with styrene is examined in the presence of a panel of ten ruthenium complexes. Our results, focusing on the catalysts' activity and selectivity, showcased the new NHC-containing complex 10 and the Fischer carbene 7 as leading to best chemoselectivities for cyclopropanation while the bidentate Schiff-base complexes 3 and 4 provided highest stereoselectivity. The traditionally metathesis-active Grubbs I catalyst (5) could be manipulated, by working under high dilution, to display moderate activity in cyclopropanation whereas the Grubbs II catalyst (6) totally promoted metathesis. Data obtained with the above set of Ru complexes strongly support the premise that ligand structure and configuration in the Ru coordination sphere are essential factors in controlling the reaction pathways. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2014.02.009
• 作为试剂：
  描述：

  苯乙烯 、 重氮乙酸乙酯 在 作用下， 以 甲苯 为溶剂， 以45.946%的产率得到
  参考文献：
  名称：

  钌配合物催化竞争反应中的类胡萝卜素转移

  摘要：

  为了提高催化剂活性，已经研究了十种钌助催化剂在类胡萝卜素从重氮乙酸乙酯转化为苯乙烯作为模型底物的过程中。新型NHC-Ru络合物10以及费歇尔卡宾7均可实现最佳的环丙烷化选择性。强调了格拉布斯第一代催化剂在这一多方面过程中令人惊讶的非金属行为。版权所有©2014 John Wiley＆Sons，Ltd.

  DOI：

  10.1002/aoc.3094