[Co(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η4-P2C2(t-C4H9)2)W(CO)5] | 388606-96-0

• 英文名称: [Co(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η4-P2C2(t-C4H9)2)W(CO)5]
• CAS: 388606-96-0
• 化学式: C₂₅H₃₆CoO₅P₅W
• 分子量: 814.27
• InChiKey: DWJJJRCPJIUOJD-UHFFFAOYSA-N

计算性质

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反应信息

• 作为产物：
  描述：

  六羰基钨 、 [Co(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)] 在 THF 作用下， 以 四氢呋喃 为溶剂， 生成 [Co(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η4-P2C2(t-C4H9)2)W(CO)5]
  参考文献：
  名称：

  Metal vapour synthesis of phospha-organometallic compounds via reaction of cobalt atoms with the phospha-alkyne tBuCP: synthesis and structural characterisation of the sandwich compounds [Co(η5-P3C2tBu2)(η4-P2C2tBu2)], [Co(η5-P2C3tBu3)(η4-P2C2tBu2)] and the protonated tetraphospha-barrelene complex [Co(η4-P4C4tBu4H)(η4-P2C2tBu2)], the latter as its [W(CO)5] adduct

  摘要：

  The reaction of cobalt atoms with ' BuC dropP gives the sandwich compounds [Co(eta (5)-P3C2' Bu-2)(eta (4)-P2C2' Bu-2)] and [Co(eta (5)-P2C3' Bu-3)], which have both been structurally characterised by single crystal X-ray diffraction studies. The novel P2C3' Bu-3)(eta (4)-P2C2' Bu-2)] protonated tetraphospha-barrelene complex [Co(eta (P4C4)-P-4' Bu4H)(eta (4)-(P2C2Bu2)-Bu-')] is also formed in the reaction and has been structurally characterised as its [W(CO)(5)] adduct. Variable temperature NMR spectra of these complexes are reported and discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01110-x