[Zn(η2-(O2CCH=CHC5H4)Fe(C5H5))2(CH3OH)2] | 1101382-64-2

• 英文名称: [Zn(η2-(O2CCH=CHC5H4)Fe(C5H5))2(CH3OH)2]
• CAS: 1101382-64-2
• 化学式: C₂₈H₃₀Fe₂O₆Zn
• 分子量: 639.627
• InChiKey: OKPIIEPVEUQIPO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Zn(η2-(O2CCH=CHC5H4)Fe(C5H5))2(CH3OH)2] 、 三(2-苯并咪唑甲基)胺 以 四氢呋喃 、 甲醇 为溶剂， 以65%的产率得到[Zn((O2CCH=CHC5H4)Fe(C5H5))(N,N-bis(1H-benzimidazol-2-ylmethyl)-1H-benzimidazole-2-methanamine)]*CH3OH
  参考文献：
  名称：

  The synthesis of complexes using precursor complexes with ferrocenyl carboxylate units as building blocks

  摘要：

  Using ferrocenyl carboxylates as functional ligands, we synthesized a mononuclear complex [Zn(eta(2)-OOCCH= CHFc)(2)(CH3OH)(2)] (1) and a binuclear complex [Cd(bafca)(2)(H2O)(2)](2) (2) (bafca = alpha-benzamido-beta-ferrocenylacrylic carboxylate) as precursor complexes. Investigation on the substitution reaction of precursor complexes as building blocks in solution-state, four complexes [Zn(OOCCH=CHFc)(2)(bbbm)](n) (1a), {[Zn(OOCCH=CHFc)(ntb)](CH3OH)} (1b), [Cd(bafca)(2)(2,2'-bpy)](2) center dot 9H(2)O (2a) and {[Cd(bafca) (2)(bbbm)(CH3OH)(2)] center dot 6CH(3)OH}(n) (2b) were obtained (bbbm = 1,1-(1,4-Butanediyl) bis-1H-benzimidazole, ntb = N, N-bis(1H-benzimidazol-2-ylmethyl)-1H-Benzimidazole-2-methanamine and 2,2'-bpy = 2,2'-bipyridine). As anticipated, the structural integrity of precursor complexes can be maintained in these four complexes. It indicates that we can synthesize the desired complexes with the destination structures by using precursor complexes as building blocks and choosing appropriate auxiliary ligands. In addition, the electrochemical properties of all complexes were investigated, and it can be seen from the results that half-wave potentials of these complexes are slightly higher than that of the corresponding ligand. (C) 2008 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2008.10.008
• 作为产物：
  描述：

  甲醇 、 sodium β-ferrocenylacrylate 、 zinc(II) acetate dihydrate 以 甲醇 、 水 为溶剂， 以68%的产率得到[Zn(η2-(O2CCH=CHC5H4)Fe(C5H5))2(CH3OH)2]
  参考文献：
  名称：

  The synthesis of complexes using precursor complexes with ferrocenyl carboxylate units as building blocks

  摘要：

  Using ferrocenyl carboxylates as functional ligands, we synthesized a mononuclear complex [Zn(eta(2)-OOCCH= CHFc)(2)(CH3OH)(2)] (1) and a binuclear complex [Cd(bafca)(2)(H2O)(2)](2) (2) (bafca = alpha-benzamido-beta-ferrocenylacrylic carboxylate) as precursor complexes. Investigation on the substitution reaction of precursor complexes as building blocks in solution-state, four complexes [Zn(OOCCH=CHFc)(2)(bbbm)](n) (1a), {[Zn(OOCCH=CHFc)(ntb)](CH3OH)} (1b), [Cd(bafca)(2)(2,2'-bpy)](2) center dot 9H(2)O (2a) and {[Cd(bafca) (2)(bbbm)(CH3OH)(2)] center dot 6CH(3)OH}(n) (2b) were obtained (bbbm = 1,1-(1,4-Butanediyl) bis-1H-benzimidazole, ntb = N, N-bis(1H-benzimidazol-2-ylmethyl)-1H-Benzimidazole-2-methanamine and 2,2'-bpy = 2,2'-bipyridine). As anticipated, the structural integrity of precursor complexes can be maintained in these four complexes. It indicates that we can synthesize the desired complexes with the destination structures by using precursor complexes as building blocks and choosing appropriate auxiliary ligands. In addition, the electrochemical properties of all complexes were investigated, and it can be seen from the results that half-wave potentials of these complexes are slightly higher than that of the corresponding ligand. (C) 2008 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2008.10.008