| 1580003-95-7

• CAS: 1580003-95-7
• 化学式: C₂₆H₃₄Cl₂N₂O₂Pd
• 分子量: 583.894
• InChiKey: XBCPFEWHOGMUDW-CSBFPTJASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-[2-(N,N-dimethylamino)ethyl]maleimide 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 135.0h， 生成
  参考文献：
  名称：

  Heteropolymetallic Complexes Linked to a 9,10-Dihydroanthracenyl Frame. Ruthenium as Active Spectator for Palladium Reactivity

  摘要：

  New monometallic Pd(II) (3, 4) and heteropolymetallic Pd(II)/Ru(II) complexes (5, 6) linked to an original 9,10-dihydroanthracenyl pyrrolidine scaffold were synthesized and fully characterized. For monometallic complexes, exo-3 and endo-4 conformers were exclusively obtained from Pd(OAc)(2) and [PdCl2(COD)], respectively. The formation of the sterically hindered endo-4 was justified by the positive noncovalent intramolecular Cl-pi interaction, observed by X-ray diffraction. The reaction of endo-4 with 1 and 2 equiv of [RuCp(NCMe)(3)]PF6 led to complexes 5 and 6, respectively. It is worth noting that lower conversions in the Suzuki-Miyaura coupling were found using 5 and 6 as catalysts, in comparison to those with monometallic palladium complexes. This behavior could be related to the higher stabilization of Pd(II) species for the heteropolymetallic complexes, as proven by electrochemical analyses.

  DOI：

  10.1021/om5001502
• 作为试剂：
  描述：

  4-溴苯甲醚 、 苯硼酸 在 C₂₆H₃₄Cl₂N₂O₂Pd 、 sodium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 2.5h， 以100%的产率得到4-甲氧基联苯
  参考文献：
  名称：

  Heteropolymetallic Complexes Linked to a 9,10-Dihydroanthracenyl Frame. Ruthenium as Active Spectator for Palladium Reactivity

  摘要：

  New monometallic Pd(II) (3, 4) and heteropolymetallic Pd(II)/Ru(II) complexes (5, 6) linked to an original 9,10-dihydroanthracenyl pyrrolidine scaffold were synthesized and fully characterized. For monometallic complexes, exo-3 and endo-4 conformers were exclusively obtained from Pd(OAc)(2) and [PdCl2(COD)], respectively. The formation of the sterically hindered endo-4 was justified by the positive noncovalent intramolecular Cl-pi interaction, observed by X-ray diffraction. The reaction of endo-4 with 1 and 2 equiv of [RuCp(NCMe)(3)]PF6 led to complexes 5 and 6, respectively. It is worth noting that lower conversions in the Suzuki-Miyaura coupling were found using 5 and 6 as catalysts, in comparison to those with monometallic palladium complexes. This behavior could be related to the higher stabilization of Pd(II) species for the heteropolymetallic complexes, as proven by electrochemical analyses.

  DOI：

  10.1021/om5001502