| 239475-79-7

• CAS: 239475-79-7
• 化学式: C₂₈H₁₉MnNO₄P
• 分子量: 519.375
• InChiKey: FZYFXQRRDSVWND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二硫化碳 、 以 二硫化碳 为溶剂， 生成 (μ3-CS3)2Mn4(CO)16
  参考文献：
  名称：

  Reactions of cyclomanganated complexes with carbon disulfide: routes to η2-aryldithiocarboxylate-Mn(CO)4 complexes and to the trithiocarbonate complex (μ3-CS3)2Mn4(CO)16

  摘要：

  Reaction of cyclomanganated aryl ketones with CS2 proceeds with insertion into the Mn-C bond to give eta(2)-dithiocarboxylato-Mn(CO)(4) compounds. With other cyclomanganated substrates such as that from Ph3P=S and also with Mn-2(CO)(10), CS2 gives (mu(3)-CS3)(2)Mn-4(CO)(16) with bridging trithiocarbonate ligands. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)02024-7
• 作为产物：
  描述：

  benzylpentacarbonylmanganese 、 四苯基氨化膦 以 正庚烷 为溶剂， 以64%的产率得到
  参考文献：
  名称：

  Orthomanganation of the iminophosphorane Ph3PNPh, and of triphenylarsine-oxide and -sulfide

  摘要：

  Two novel types of cyclometallated rings are described. Orthomanganation of Ph3P=NPh gave Ph2P[=NPh]C6H4Mn(CO)(4), 5a, containing an N,C-chelated five-membered ring, characterised by single crystal X-ray determinations of two distinct polymorphs. Solutions of 5a are thermochroic. The rhenium analogue of 5a was also prepared. Reaction of Ph3As=X (X=O, S) with PhCH2Mn(CO)(5) gave the first examples of orthometallated triphenylarsine chalcogenides. The example with X=O was characterised structurally. Attempted cyclomanganation of Ph3As was unsuccessful, but gave (in low yield) a dimanganese complex containing mu-AsPh2 and mu-eta(1), eta(6)-benzyl ligands. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00007-8