cis-[Re2(CH3COO)2Cl4(N,N-dimethylacetamide)2] | 74278-06-1

• 英文名称: cis-[Re2(CH3COO)2Cl4(N,N-dimethylacetamide)2]
• 英文别名: cis-[Re2(CH3COO)2Cl4(DMAA)2]；cis-diacetatotetrachloro(N,N-dimethylacetamide)2dirhenate(III)
• CAS: 74278-06-1
• 化学式: C₁₂H₂₄Cl₄N₂O₆Re₂
• 分子量: 806.558
• InChiKey: GPELXRPOUXZHKO-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[Re2(CH3COO)2Cl4(N,N-dimethylacetamide)2] 以 neat (no solvent) 为溶剂， 生成 trans-dirhenium diacetate tetrachloride
  参考文献：
  名称：

  Synthesis and Crystal Structure of the [Re₂(CH₃COO)₂Cl₄((CH₃)₂NCOCH₃)₂] Complex

  摘要：

  Compound [Re-2(CH3COO)(2)Cl-4((CH3)(2)NCOCH3)(2)] is synthesized. The influence of parameters of the hydrothermal synthesis under elevated pressure on the yield of a target product and its molecular structure and physicochemical properties is studied. In the neutral complex with cis-arrangement of the bridging acetate and terminal chloride ligands with respect to the multiply bonded Re-2(6+) complex-forming center, the Re-Re bond length is 2.2418(3) Angstrom. Dimethylacetamide molecules are in the axial positions, the Re-O bond lengths being 2.304(3) and 2.321(4) Angstrom. The influence of the donor ability of the axial substituents in analogous structures of the rhenium(III) binuclear clusters on the Re-Re and Re-L-ax bond lengths is analyzed.

  DOI：

  10.1023/b:ruco.0000047465.70746.fd
• 作为产物：
  描述：

  盐酸 、 高铼酸钾 、 N,N-二甲基乙酰胺 、 溶剂黄146 以 盐酸 、 溶剂黄146 为溶剂， 生成 cis-[Re2(CH3COO)2Cl4(N,N-dimethylacetamide)2]
  参考文献：
  名称：

  Synthesis and Crystal Structure of the [Re₂(CH₃COO)₂Cl₄((CH₃)₂NCOCH₃)₂] Complex

  摘要：

  Compound [Re-2(CH3COO)(2)Cl-4((CH3)(2)NCOCH3)(2)] is synthesized. The influence of parameters of the hydrothermal synthesis under elevated pressure on the yield of a target product and its molecular structure and physicochemical properties is studied. In the neutral complex with cis-arrangement of the bridging acetate and terminal chloride ligands with respect to the multiply bonded Re-2(6+) complex-forming center, the Re-Re bond length is 2.2418(3) Angstrom. Dimethylacetamide molecules are in the axial positions, the Re-O bond lengths being 2.304(3) and 2.321(4) Angstrom. The influence of the donor ability of the axial substituents in analogous structures of the rhenium(III) binuclear clusters on the Re-Re and Re-L-ax bond lengths is analyzed.

  DOI：

  10.1023/b:ruco.0000047465.70746.fd