trans-dirhenium diacetate tetrachloride | 100495-10-1

• 英文名称: trans-dirhenium diacetate tetrachloride
• 英文别名: trans-[Re2(CH3COO)2Cl4]
• CAS: 100495-10-1
• 化学式: C₄H₆Cl₄O₄Re₂
• 分子量: 632.315
• InChiKey: UEARYFBRXJTNFG-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-dirhenium diacetate tetrachloride 在 溶剂黄146 作用下， 以 溶剂黄146 为溶剂， 生成 tetrakis(acetato)dichloridodirhenium(III,III)
  参考文献：
  名称：

  Shtemenko, A. V.; Bovykin, B. A.; Shram, V. P., Russian Journal of Inorganic Chemistry, 1985, vol. 30, p. 1753 - 1755

  摘要：

  DOI：
• 作为产物：
  描述：

  cis-[Re2(CH3COO)2Cl4(N,N-dimethylacetamide)2] 以 neat (no solvent) 为溶剂， 生成 trans-dirhenium diacetate tetrachloride
  参考文献：
  名称：

  Synthesis and Crystal Structure of the [Re₂(CH₃COO)₂Cl₄((CH₃)₂NCOCH₃)₂] Complex

  摘要：

  Compound [Re-2(CH3COO)(2)Cl-4((CH3)(2)NCOCH3)(2)] is synthesized. The influence of parameters of the hydrothermal synthesis under elevated pressure on the yield of a target product and its molecular structure and physicochemical properties is studied. In the neutral complex with cis-arrangement of the bridging acetate and terminal chloride ligands with respect to the multiply bonded Re-2(6+) complex-forming center, the Re-Re bond length is 2.2418(3) Angstrom. Dimethylacetamide molecules are in the axial positions, the Re-O bond lengths being 2.304(3) and 2.321(4) Angstrom. The influence of the donor ability of the axial substituents in analogous structures of the rhenium(III) binuclear clusters on the Re-Re and Re-L-ax bond lengths is analyzed.

  DOI：

  10.1023/b:ruco.0000047465.70746.fd

文献信息

• Shtemenko, A. V.; Bagirov, Sh. A.; Kotel'nikova, A. S., Russian Journal of Inorganic Chemistry, 1981, vol. 26, p. 58 - 60
  作者：Shtemenko, A. V.、Bagirov, Sh. A.、Kotel'nikova, A. S.、Lebedev, V. N.、Kazymov, O. I.、Alieva, A. I.

  DOI：——

  日期：——
• Chen, Jhy-Der; Cotton, F. Albert, Journal of the American Chemical Society, 1991, vol. 113, # 7, p. 2509 - 2512
  作者：Chen, Jhy-Der、Cotton, F. Albert

  DOI：——

  日期：——
• Synthesis and Characterization of Conjugated Polymers Containing Rhenium-Rhenium Quadruple Bonds
  作者：Andrew C. Price、Scott T. Trzaska、Robert E. Lee Trout

  DOI：10.1080/00945719809351700

  日期：1998.10