氮 、 氙气 以
neat (no solvent) 为溶剂,
以0%的产率得到dinitrogen compound with xenon (1:1)
参考文献:
名称:
FTIR spectra of liquid argon/liquid nitrogen mixtures: evidence for the existence of a 1:1 bonded species Ar·N2
摘要:
The mid-infrared spectra of liquid phase argon/nitrogen (80-121 K), krypton/nitrogen (78-121 K) and xenon/nitrogen (80-123 K) mixtures are reported. Superposed on the broad, collision-induced N-2 band, for the Ar/N-2 and the Kr/N-2 mixtures a weak band, proving the existence of a 1:1 species Ar . N-2 or Kr . N-2, was observed near 2326 cm(-1). Using spectra recorded at different temperatures, the complexation enthalpy of Ar . N-2 was determined to be -1.5(4) kJ mol(-1). (C) 1998 Elsevier Science B.V. All rights reserved.