tetra-n-butylammonium dichloro[2-(2-quinolyl)phenyl-3-ido]platinum | 223661-68-5

• 英文名称: tetra-n-butylammonium dichloro[2-(2-quinolyl)phenyl-3-ido]platinum
• 英文别名: ((n)Bu4N)[Pt(NC13H8)Cl2]；(NBu4)[PtCl2(benzo[h]quinoline(1-))2]；(Bu4N)[PtCl2(benzo[h]quinoline)；[Bu4N][Pt(benzoquinolinate)Cl2]
• CAS: 223661-68-5
• 化学式: C₁₃H₈Cl₂NPt*C₁₆H₃₆N
• 分子量: 686.668
• InChiKey: LXFBQIZSKJKHLE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  7-氮杂吲哚 、 tetra-n-butylammonium dichloro[2-(2-quinolyl)phenyl-3-ido]platinum 在 NaH 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 以74%的产率得到[Pt(NC13H8)(μ-N2C7H5)]2
  参考文献：
  名称：

  通过使用具有预先设计的几何形状的N-供体桥合成有机铂低聚物：发光的环金属化铂（II）大环的结构和光物理性质

  摘要：

  一系列发光的二聚和三聚环金属化铂（II）大环，即[Pt（CN ）（NN ）] 2（N =吡唑酸酯，pz（2）； 7-氮杂吲哚酸酯，氮杂（3）; CN = 2-（2'-噻吩基）吡啶基，Thpy（a）; 7,8-苯并喹啉酸酯，Bzqn（b）; 2-苯基吡啶基，Phpy（c））和[Pt（CN ）（ [N-N）] 3（N-N =苯并咪唑酯，bzim（4）； C = N = Thpy（a）和Bzqn（b）），以高收率（70-90％）合成。pz，aza和bzim桥接配体的刚性，预定义的配位几何结构确保了各个环状低聚物的高效选择性组装。1a和4a的晶体结构中的堆叠排列揭示了2-（2'-噻吩基）吡啶基部分之间的π-π相互作用。UV-vis光谱中的最低能量吸收带分配给金属到配体的电荷转移（MLCT）跃迁。配合物2 − 4a的298 K流体排放带有Thpy配体的分子具有MLCT和IL（配位体）混合特征。在晶体

  DOI：

  10.1021/om990342h
• 作为产物：
  描述：

  四丁基氯化铵 在 (piperidinomethyl)polystyrene 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 反应 48.0h， 生成 tetra-n-butylammonium dichloro[2-(2-quinolyl)phenyl-3-ido]platinum
  参考文献：
  名称：

  简单铂 (II) 前体的光化学诱导环金属化

  摘要：

  使用 (Bu 4 N) 2 [Pt 2 ] 演示了 2-芳基吡啶和相关 C∧N 配体以及三齿杂芳族 N∧N∧C、N∧C∧N 和 N∧C∧C 化合物的光化学环铂化Cl 6 ] 或 [PtCl 2 (NCPh) 2 ] 在室温下作为前体。根据激发波长和前体，可获得具有 C∧N 配体的单环金属化或双环金属化 Pt(II) 配合物。监测实验表明，光激发可以实现 N 配位和随后的 C-H 金属化。已经开发了光化学合成方案，这有利于已建立的热程序，并允许合成第一个带有 N∧C∧C 配体的 Pt(II) 配合物。

  DOI：

  10.1021/acs.inorgchem.3c00688

文献信息

• Self-Assembly of Predesigned Trimetallic Macrocycles Based on Benzimidazole as Nonlinear Bridging Motifs: Crystal Structure of a Luminescent Platinum(II) Cyclic Trimer
  作者：Siu-Wai Lai、Michael Chi-Wang Chan、Shie-Ming Peng、Chi-Ming Che

  DOI：10.1002/(sici)1521-3773(19990301)38:5<669::aid-anie669>3.0.co;2-l

  日期：1999.3.1

  A trimetallic macrocycle: Starting from nonlinear N-deprotonated benzimidazole and square-planar cyclometalated platinum(II) precursors, cyclic trimers with three metal vertices can be obtained by a general and rational strategy (shown schematically, M=Pt). A complex is formed with 2-(2-thienyl)pyridine as chelating ligand which photoluminesces in solution at room temperature.

  三金属大环：从非线性N-去质子化的苯并咪唑和方形平面的环金属化的铂（II）前体开始，可以通过一般且合理的策略获得具有三个金属顶点的环状三聚体（示意性地显示为M = Pt）。用2-（2-噻吩基）吡啶作为螯合配体形成络合物，该络合物在室温下在溶液中光致发光。
• Structures and Luminescence Properties of Cyclometalated Dinuclear Platinum(II) Complexes Bridged by Pyridinethiolate Ions
  作者：Rie Aoki、Atsushi Kobayashi、Ho-Chol Chang、Masako Kato

  DOI：10.1246/bcsj.20100304

  日期：2011.2.15

  A series of cyclometalated dinuclear platinum(II) complexes bridged by pyridine-2-thiolate (pyt) ions, [Pt2(L)2(pyt)2] (HL = 2-(p-tolyl)pyridine (Hptpy), 2-(2-thienyl)pyridine (Hthpy), or benzo[h]quinoline (Hbzqn)), as well as their two-electron-oxidized dinuclear platinum(III) complexes, [Pt2Cl2(L)2(pyt)2], have been synthesized and characterized. The structures and luminescence properties have been investigated by comparing them with those of the corresponding 2-phenylpyridinato (ppy) complex. All divalent complexes have similar dinuclear frameworks, with short Pt···Pt distances (ca. 2.85 Å), and exhibit similar intense luminescence from the triplet metal–metal-to-ligand charge-transfer (3MMLCT) state in glassy solutions. However, they provide different luminescence features reflecting their dynamic behaviors in fluid solutions and their intermolecular interactions in the solid state. [Pt2(bzqn)2(pyt)2] containing fused aromatic rings exhibits the most sensitive features to the environment, i.e., it shows the most red-shifted luminescence spectrum in the solid state due to the intermolecular π–π interaction. However, in fluid solution, it provides very weak luminescence based on a rapid nonradiative deactivation mainly caused by the fluctuation of the intramolecular π–π repulsion between the ligands. [Pt2(ptpy)2(pyt)2], on the other hand, is the most stable luminophore, which always exhibits intense luminescence with an almost constant emission maximum independent of its temperature and state.

  一系列由吡啶-2-硫醇盐 (pyt) 离子桥接的环金属化双核铂 (II) 配合物，[Pt2(L)2(pyt)2] (HL = 2-(对甲苯基)吡啶 (Hptpy), 2- (2-噻吩基)吡啶 (Hthpy) 或苯并[h]喹啉 (Hbzqn)) 及其双电子氧化双核铂 (III) 配合物 [Pt2Cl2(L)2(pyt)2] 具有进行了合成和表征。通过与相应的 2-苯基吡啶 (ppy) 配合物进行比较，研究了其结构和发光性质。所有二价配合物都具有相似的双核骨架，具有短的 Pt·Pt 距离（约 2.85 Å），并且在玻璃溶液中的三线态金属-金属-配体电荷转移 (3MMLCT) 状态下表现出相似的强发光。然而，它们提供不同的发光特征，反映它们在流体溶液中的动态行为以及它们在固态中的分子间相互作用。含有稠合芳环的[Pt2(bzqn)2(pyt)2]表现出对环境最敏感的特征，即由于分子间π-π相互作用，它在固态下显示出最红移的发光光谱。然而，在流体溶液中，它基于快速非辐射失活而提供非常弱的发光，这主要是由配体之间的分子内 π-π 排斥力的波动引起的。另一方面，[Pt2(ptpy)2(pyt)2] 是最稳定的发光体，它总是表现出强烈的发光，并且无论其温度和状态如何，其发射最大值几乎恒定。
• Metal–Metal-to-Ligand Charge Transfer in Pt(II) Dimers Bridged by Pyridyl and Quinoline Thiols
  作者：Subhangi Roy、Antonio A. Lopez、James E. Yarnell、Felix N. Castellano

  DOI：10.1021/acs.inorgchem.1c02469

  日期：2022.1.10

  properties of these molecules. All five molecules reported (anti-[Pt(ppy)(μ-Mpyt)]2 could not be isolated), three of which are newly conceived here, possess electronic absorptions past 500 nm and high quantum yield PL emission with spectra extending into the far red (λem > 700 nm), originating from the charge-transfer state in each instance. Each chromophore displays excited-state decay kinetics adequately

  基于反-[Pt(C ∧ N)(μ-N ∧ S)] 2的两种不同种类的方形平面双核 Pt(II) 二聚体的研究，其中 C ∧ N 是 2-苯基吡啶 (ppy) 或苯并( h ) 喹啉 (bzq) 和 N ∧ S 是吡啶-2-硫醇 (pyt)、6-甲基吡啶-2-硫醇 (Mpyt) 或 2-喹啉硫醇 (2QT)。每个分子都通过电子结构计算、静态 UV-vis 和光致发光 (PL) 光谱、循环伏安法以及瞬态吸光度和时间门控 PL 实验进行了彻底的表征。这些可见的吸收发色团具有源自分子内 d 的金属-金属-配体电荷转移 (MMLCT) 激发态8 -d 8金属-金属 σ-相互作用，并表现在这些分子的基态和激发态特性中。报告的所有五种分子（抗-[Pt(ppy)(μ-Mpyt)] 2无法分离），其中三种是这里新构思的，具有超过 500 nm 的电子吸收和高量子产率 PL 发射，光谱延伸到远红（λ em> 700
• Structural and Luminescence Studies on π···π and Pt···Pt Interactions in Mixed Chloro-Isocyanide Cyclometalated Platinum(II) Complexes^†
  作者：Álvaro Díez、Juan Forniés、Carmen Larraz、Elena Lalinde、José A. López、Antonio Martín、M. Teresa Moreno、Violeta Sicilia

  DOI：10.1021/ic902094c

  日期：2010.4.5

  [Pt(bzq)CI(CNR)] [bzq = benzoquinolinate; R = tert-butyl (Bu-1 1), 2-6-dimethylphenyl (Xyl 2), 2-naphthyl (2-Np 3)] complexes have been synthesized and structurally and photophysically characterized. 1 was found to co-crystallize in two distinct pseudopolymorphs: a red form, which exhibits an infinite 1D-chain ([1](infinity)) and a yellow form, which contains discrete dimers ([1](2)), both stabilized by interplanar pi center dot center dot center dot pi (bzq) and short Pt center dot center dot center dot Pt bonding interactions. Complex 3, generated through the unexpected garnet-red double salt isomer [Pt(bzq)(CN-2-Np)(2)][Pt(bzq)Cl-2] 4, crystallizes as yellow Pt center dot center dot center dot Pt dimers ([3](2)), while 2 only forms pi center dot center dot center dot pi (bzq) contacting dimers, Their electronic absorption and luminescence behaviors have been investigated. According to Time-Dependent Density Functional Theory (TD-DFT) calculations, the lowest-lying absorption (CH2Cl2) has been attributed to combined (ILCT)-I-1 and (MLCT)-M-1/(ML)-M-1'CT (L = bzq, L' = CNR) transitions, the latter increasing from 1 to 3. In solid state, while the yellow form [1](2) exhibits a green (MLCT)-M-3 unstructured emission only at 77 K, the 1-D form [1](infinity) displays a characteristic low-energy red emission (672 nm, 298 K; 744 nm, 77 K) attributed to a mixed 3MMCT [d(sigma*) p(sigma)]/(MMLCT)-M-3 [d sigma*(M-2)->sigma(pi*)(bzq)] excited state. However, upon exposure to standard atmospheric conditions, Ii],.. shows an irreversible change to an orangeochre solid, whose emissive properties are similar to those of the crude 1. Complexes 2 and 3 (77 K) exhibit a structured emission from discrete fragments ((LC)-L-3/(MLCT)-M-3), whereas the luminescence of the garnet-red salt 4 is dominated by a low energy emission (680 nm, 298 K; 730 nm, 77 K) arising from a (MMLCT)-M-3 excited state. Solvent (CH2Cl2, toluene, 2-MeTHF and CH3CN) and concentration-dependent emission studies at 298 K and at 77 K are also reported for 1-3. In CH2Cl2 solution, the low phosphorescent emission band is ascribed to bzq intraligand charge transfer (ILCT)-I-3 mixed with metal-to-ligand (L = bzq, L' = CNR) charge transfer (MLCT)-M-3/(ML)-M-3'CT character with the Pt to CNR contribution increasing from 1 to 3, according to computational studies.
• ——
  作者：M. V. Kulikova、T. V. Taraskina、E. A. Cherezova、K. P. Balashev

  DOI：10.1023/a:1026159608823

  日期：——