| 927889-01-8

• CAS: 927889-01-8
• 化学式: C₇₂H₆₄B₂F₄N₄
• 分子量: 1082.94
• InChiKey: ALLCYPUMDOQPOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 对二甲氨基苯甲醛 在 哌啶 、 溶剂黄146 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以32%的产率得到
  参考文献：
  名称：

  Signal Ratio Amplification via Modulation of Resonance Energy Transfer:  Proof of Principle in an Emission Ratiometric Hg(II) Sensor

  摘要：

  Boradiazaindacene dyads designed as energy transfer casettes can be modified to signal cation concentrations ratiometrically. If the energy transfer efficiency is increased via changing spectral overlap on cation binding, an enhancement of emission signal ratios can be obtained. A larger range of ratios results in highly improved sensitivity to analyte concentrations. We demonstrate this approach in a de novo design of a novel and highly selective ratiometric chemosensor for Hg(II) ions.

  DOI：

  10.1021/ja066144g
• 作为产物：
  描述：

  1,4-bis((4-((trimethylsilyl)ethynyl)phenyl)ethynyl)benzene 在 palladium dichloride copper(l) iodide 、 potassium carbonate 、 三乙胺 、 三苯基膦 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 16.0h， 生成
  参考文献：
  名称：

  Signal Ratio Amplification via Modulation of Resonance Energy Transfer:  Proof of Principle in an Emission Ratiometric Hg(II) Sensor

  摘要：

  Boradiazaindacene dyads designed as energy transfer casettes can be modified to signal cation concentrations ratiometrically. If the energy transfer efficiency is increased via changing spectral overlap on cation binding, an enhancement of emission signal ratios can be obtained. A larger range of ratios results in highly improved sensitivity to analyte concentrations. We demonstrate this approach in a de novo design of a novel and highly selective ratiometric chemosensor for Hg(II) ions.

  DOI：

  10.1021/ja066144g