(η4-exo-Ph3SiC5H5)Fe(CO)2(PPh3) | 259108-43-5

• 英文名称: (η4-exo-Ph3SiC5H5)Fe(CO)2(PPh3)
• CAS: 259108-43-5
• 化学式: C₄₃H₃₅FeO₂PSi
• 分子量: 698.656
• InChiKey: QSNDKRZRRFHUKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 (η4-exo-Ph3SiC5H5)Fe(CO)2(PPh3) 以 水 为溶剂， 生成
  参考文献：
  名称：

  Deprotonation Pathway in the Reaction of Me₆Si₂ with MeLi

  摘要：

  A mixture of 3 mol of Me6Si2 and 1 mol of MeLi in the presence of Pi(O)(NMe2)(3) produced Me3SiLi as the initial product. This then deprotonated excess Me-6- Sit and started an unprecedented transformation leading to (Me3Si)(2)(SiMe2H)CLi (3), whose quench by [(eta(5)-C5H5)Fe(Co)(2)PPh3+] produced {eta(4)-exo-[(Me3Si)(2)C-(SiMe2H)]C5H5}Fe(Co)(2)(PPh3) (2e). In the literature the reaction of Me6Si2 and MeLi gives Me3SiLi and/or Me3SiSiMe2Li (4). The lithium compound 3 is the major product when a previously unnoticed deprotonation pathway Is enhanced by use of an excess of Me6Si2 and a longer reaction time.

  DOI：

  10.1021/om9908175
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 、 三苯基氯硅烷 、 三苯基膦 在 Li 作用下， 以 四氢呋喃 为溶剂， 以51%的产率得到(η4-exo-Ph3SiC5H5)Fe(CO)2(PPh3)
  参考文献：
  名称：

  Deprotonation Pathway in the Reaction of Me₆Si₂ with MeLi

  摘要：

  A mixture of 3 mol of Me6Si2 and 1 mol of MeLi in the presence of Pi(O)(NMe2)(3) produced Me3SiLi as the initial product. This then deprotonated excess Me-6- Sit and started an unprecedented transformation leading to (Me3Si)(2)(SiMe2H)CLi (3), whose quench by [(eta(5)-C5H5)Fe(Co)(2)PPh3+] produced {eta(4)-exo-[(Me3Si)(2)C-(SiMe2H)]C5H5}Fe(Co)(2)(PPh3) (2e). In the literature the reaction of Me6Si2 and MeLi gives Me3SiLi and/or Me3SiSiMe2Li (4). The lithium compound 3 is the major product when a previously unnoticed deprotonation pathway Is enhanced by use of an excess of Me6Si2 and a longer reaction time.

  DOI：

  10.1021/om9908175