| 97633-56-2

• CAS: 97633-56-2
• 化学式: C₁₅H₁₀O₁₀Ru₃
• 分子量: 653.448
• InChiKey: MYLLDNOSTMYIEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 氢气 作用下， 以 环己烷 为溶剂， 以43%的产率得到
  参考文献：
  名称：

  在三钌簇上的亚甲基-炔偶联和簇结合的1，3-二金属烯丙基单元的氢化。费托链增长的新模式

  摘要：

  DOI：

  10.1021/om00129a004
• 作为产物：
  描述：

  2-丁炔 、 H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 以 环己烷 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  在三钌簇上的亚甲基-炔偶联和簇结合的1，3-二金属烯丙基单元的氢化。费托链增长的新模式

  摘要：

  DOI：

  10.1021/om00129a004

文献信息

• Alkylidyne-alkyne coupling on triruthenium clusters. A potential model for Fischer-Tropsch chain growth
  作者：Lawrence R. Beanan、Zuraidah Abdul Rahman、Jerome B. Keister

  DOI：10.1021/om50002a029

  日期：1983.8
• Structural studies on ruthenium carbonyl hydrides
  作者：Melvyn Rowen Churchill、Charles H. Lake、Romana A. Lashewycz-Rubycz、Huirong Yao、Robert D. McCargar、Jerome B. Keister

  DOI：10.1016/0022-328x(93)83184-w

  日期：1993.6

  Substitution products HRu3(mu3-eta3-XCCRCR')(CO)9-n(PPh3)n (X = OMe, R = R'= Me, n = 1-3; X = OMe, R = H, R'= OEt, n = 2, 3; X = NEt2, R = H, R' = Me, n = 1, 2) were prepared by using ONMe3-induced ligand substitution. The products were characterized by spectroscopic methods. In addition, (mu-H)Ru3(mu3-eta3-Et2NCCHCMe)(CO)8(PPh3) (Mo Kalpha, 2theta 5.0-50.0-degrees, R(F) 5.22% for all 6,374 reflections, 2.62% for those 4,306 reflections with \F(o)\ > 6sigma(\F(o)\)) and (mu-H)Ru3(mu3-eta3-MeOCCMeCMe)(CO)7(PPh3)2 . 2CH2Cl2 (Mo Kalpha, 20 8.0-45.0, RF 9.52% for all 6,798 reflections, 6.69% for those 3,795 reflections with \F(o)\ > 6sigma(\F(o)\)) were characterized by single-crystal X-ray diffraction. Both compounds crystallize in the triclinic space group P1BAR, with a 11.277(2) angstrom, b 11.899(1) angstrom, c 15.638(2) angstrom, alpha = 70.56(1), beta = 85.23(1), gamma = 66.00(1)-degrees, V = 1802.8(4) angstrom3, and Z = 2 for the former and a = 12.960(2) angstrom, b = 13.040(2) angstrom, c = 17.683(3) angstrom, a = 98.81(1), beta = 94.50(1)-degrees, gamma = 116.50(1)-degrees, V = 2606.2(8) angstrom3, and Z = 2 for the latter. In each case the PPh3 ligands are coordinated cis to the bridging hydride and to the sigma Ru-C bond.