2-methylnaphth-1-yl ferrocenoyl selenide | 779339-33-2

• 英文名称: 2-methylnaphth-1-yl ferrocenoyl selenide
• CAS: 779339-33-2
• 化学式: C₂₂H₁₈FeOSe
• 分子量: 433.191
• InChiKey: LYIAPYORUIKIFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-methylnaphth-1-yl ferrocenoyl selenide 、 苯硫酚 以 further solvent(s) 为溶剂， 以0%的产率得到二茂铁甲醛
  参考文献：
  名称：

  Synthesis, reactivity, electrochemical and crystallographic studies of diferrocenoyl diselenide and ferrocenoyl selenides

  摘要：

  Diacyl diselenide (8), diacyl selenide (9) and acyl selenol esters (10-12) incorporating the ferrocenoyl substituent have been synthesized from ferrocene carboxylic acid (13). The new compounds (8-10) have been characterized by multinuclear NMR (H-1, C-13, Se-77), IR spectroscopy and electrospray mass spectrometry. All compounds (8-13) undergo a one electron reversible oxidation at significantly more positive potential than ferrocene. The structures of the diselenide and selenide (8 and 10) have been confirmed by single crystal X-ray diffraction. The absolute structure parameter of 8 indicates that it crystallizes in an enan-tiomerically pure form. The peroxidase-like activities of the diselenide (8) and selenides (9-12) have been determined by the thiol assay. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.054
• 作为产物：
  描述：

  ferrocenoyl chloride 、 bis(2-methyl-1-naphthyl) diselenide 在 LiBHEt₃ 作用下， 以 四氢呋喃 为溶剂， 以94%的产率得到2-methylnaphth-1-yl ferrocenoyl selenide
  参考文献：
  名称：

  Synthesis, reactivity, electrochemical and crystallographic studies of diferrocenoyl diselenide and ferrocenoyl selenides

  摘要：

  Diacyl diselenide (8), diacyl selenide (9) and acyl selenol esters (10-12) incorporating the ferrocenoyl substituent have been synthesized from ferrocene carboxylic acid (13). The new compounds (8-10) have been characterized by multinuclear NMR (H-1, C-13, Se-77), IR spectroscopy and electrospray mass spectrometry. All compounds (8-13) undergo a one electron reversible oxidation at significantly more positive potential than ferrocene. The structures of the diselenide and selenide (8 and 10) have been confirmed by single crystal X-ray diffraction. The absolute structure parameter of 8 indicates that it crystallizes in an enan-tiomerically pure form. The peroxidase-like activities of the diselenide (8) and selenides (9-12) have been determined by the thiol assay. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.054