| 215317-88-7

• CAS: 215317-88-7
• 化学式: C₁₀H₂₇Cl₂Ni₂OP₃
• 分子量: 444.531
• InChiKey: BUTIIAHORROIBL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 四氢呋喃 为溶剂， 生成 monocarbonyltris(trimethylphosphine)nickel 、 nickel dichloride
  参考文献：
  名称：

  Dichlorodinickel(I) Complexes withμ2-CO orμ2-CS Bridges and Trimethylphosphane Ligands: Homologous Composition, but Different Frameworks

  摘要：

  High ligand mobility is shown by the coordinatively unsaturated nickel(I) compound 1 with a short Ni-Ni distance and an asymmetric CO bridge. The thio homologue 2 contains the novel (thiocarbonyl)trimethylphosphorane bridging ligand, which sits like a "stork's nest" on top of the roof-shaped dinuclear complex. In contrast to 1, complex 2 does not show fluctional behavior and can be methylated without decomposition. X=Cl, Me.

  DOI：

  10.1002/(sici)1521-3773(19980918)37:17<2385::aid-anie2385>3.0.co;2-y
• 作为产物：
  描述：

  Collman's reagent 、 dichlorobis(trimethylphosphine)nickel 以 not given 为溶剂， 以28%的产率得到
  参考文献：
  名称：

  Dichlorodinickel(I) Complexes withμ2-CO orμ2-CS Bridges and Trimethylphosphane Ligands: Homologous Composition, but Different Frameworks

  摘要：

  High ligand mobility is shown by the coordinatively unsaturated nickel(I) compound 1 with a short Ni-Ni distance and an asymmetric CO bridge. The thio homologue 2 contains the novel (thiocarbonyl)trimethylphosphorane bridging ligand, which sits like a "stork's nest" on top of the roof-shaped dinuclear complex. In contrast to 1, complex 2 does not show fluctional behavior and can be methylated without decomposition. X=Cl, Me.

  DOI：

  10.1002/(sici)1521-3773(19980918)37:17<2385::aid-anie2385>3.0.co;2-y