dppr(BH3)2 | 852547-15-0

• 英文名称: dppr(BH3)2
• CAS: 852547-15-0
• 化学式: C₃₄H₃₄B₂P₂Ru
• 分子量: 627.283
• InChiKey: DCUVNARNWHALIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-bis(diphenylphosphino)ruthenocene 、 borane tetrahydrofuran 以 四氢呋喃 为溶剂， 以95%的产率得到dppr(BH3)2
  参考文献：
  名称：

  Anodic Electrochemistry of Ferrocenylphosphine and Ruthenocenylphosphine Chalcogenide Complexes and Lewis Acid Adducts

  摘要：

  The anodic electrochemistry of a series of bidentate phosphine chalcogenides and bidentate phosphine Lewis acid adducts, both with a metallocene backbone, was examined in dichloromethane containing [NBu4] [PF6]. Oxidation of the ferrocene compounds dppfE(2) and dippfE(2) (E = O, S, BH3, CH3+) was reversible on the cyclic voltammetric (CV) time scale, while the oxidation of the dpprE(2) compounds (E = O, S, BH3) was irreversible; however, the oxidation of dppfSe(2), dippfSe(2), and dpprSe(2) displayed an irreversible wave and the reduction of a follow-up product.

  DOI：

  10.1021/om050074p