Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether) | 1050503-80-4

• 英文名称: Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether)
• CAS: 1050503-80-4
• 化学式: C₄H₁₀O*C₂₀H₂₀Cl₂FeN₄O₄S₄
• 分子量: 709.543
• InChiKey: OBJADDZMUVLLKB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether) 、 N,N-二甲基甲酰胺 在 air 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 Fe(2-salicyloylhydrazono-1,3-dithiolane(-1H))2(DMF)Cl
  参考文献：
  名称：

  Synthesis and Magnetic Properties of New Mono- and Binuclear Iron Complexes with Salicyloylhydrazono Dithiolane Ligand

  摘要：

  We report here experimental evidence for the formation in the solid state of a new binuclear Fe(2)(III) (mu-OMe)(2)(HL)(4) complex (H(2)L is 2-salicyloylhydrazono-1,3-dithiolane). The isostructural Mn(2)(III)(mu-OMe)(2)(HL)(4) complex has provided the strongest ferromagnetic interaction value (J approximate to 20 cm(-1)) between Mn(III) ions to date. The new iron binuclear compound presented in this study shows antiferromagnetic intramolecular coupling, which agrees with the theoretical study that we previously proposed. During our synthetic work, we also observed an unexpected spontaneous reduction of the new Fe(III)(HL)(2)Cl,S complex to the new Fe(II)(H(2)L)(2)Cl(2) high-spin mononuclear complex. This process has been checked by cyclo-voltammetry as well as pseudosteady voltammetry.

  DOI：

  10.1021/ic800522h
• 作为产物：
  描述：

  乙醚 、 2-salicyloylhydrazono-1,3-dithiolane 、 三氯化铁 以 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到Fe(2-salicyloylhydrazono-1,3-dithiolane)2Cl2*(diethyl ether)
  参考文献：
  名称：

  Synthesis and Magnetic Properties of New Mono- and Binuclear Iron Complexes with Salicyloylhydrazono Dithiolane Ligand

  摘要：

  We report here experimental evidence for the formation in the solid state of a new binuclear Fe(2)(III) (mu-OMe)(2)(HL)(4) complex (H(2)L is 2-salicyloylhydrazono-1,3-dithiolane). The isostructural Mn(2)(III)(mu-OMe)(2)(HL)(4) complex has provided the strongest ferromagnetic interaction value (J approximate to 20 cm(-1)) between Mn(III) ions to date. The new iron binuclear compound presented in this study shows antiferromagnetic intramolecular coupling, which agrees with the theoretical study that we previously proposed. During our synthetic work, we also observed an unexpected spontaneous reduction of the new Fe(III)(HL)(2)Cl,S complex to the new Fe(II)(H(2)L)(2)Cl(2) high-spin mononuclear complex. This process has been checked by cyclo-voltammetry as well as pseudosteady voltammetry.

  DOI：

  10.1021/ic800522h