{bis({(2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}(chloro)rhodium(I))(bis(pyrazol-1-yl)methyl)} | 95248-14-9

• 英文名称: {bis({(2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}(chloro)rhodium(I))(bis(pyrazol-1-yl)methyl)}
• CAS: 95248-14-9；153295-03-5
• 化学式: C₂₁H₂₄Cl₂N₄Rh₂
• 分子量: 609.165
• InChiKey: KFQSAWKISFUJHV-PPJNSWHOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(norbornadiene)rhodium(I)chloride]2 、 1-(1-吡唑甲基)吡唑 以 丙酮 为溶剂， 以82%的产率得到{bis({(2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene}(chloro)rhodium(I))(bis(pyrazol-1-yl)methyl)}
  参考文献：
  名称：

  Rhodium(I) complexes with bis(pyrazolyl)methane ligands. Crystal structure of [Rh(COD)(CH2(Pz)2)]ClO4· C2H4Cl2

  摘要：

  DOI：

  10.1016/0022-328x(84)80606-3

文献信息

• (2,5-Norbornadiene)rhodium(I) complexes with bis- and tris(azol-1-yl)methanes
  作者：Paloma Ballesteros、Concepcion Lopez、Carmen Lopez、Rosa M. Claramunt、Jose A. Jimenez、Mercedes Cano、Jose V. Heras、Elena Pinilla、Angeles Monge

  DOI：10.1021/om00013a042

  日期：1994.1

  Reactions of bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]bis(mu-chloro)dirhodium, [RhCl-(NBD)]2, with bis- and tris(azolyl)methanes have been performed in methanol and acetone with 1:1 and 1:2 [RhCl(NBD)]2/ligand molar ratios. The structures of the complexes have been characterized by infrared and H-1 and C-13 NMR spectroscopy as well as X-ray diffraction analysis. Cationic species have been evidenced in the solid state while equilibria between cationic and neutral species have been established in solution.