[(η(5)-pentamethylcyclopentadienyl)IrCl(η(2)-Ph2P(Se)CH2P(Se)Ph2-Se,Se')]BF4 | 165902-47-6

• 英文名称: [(η(5)-pentamethylcyclopentadienyl)IrCl(η(2)-Ph2P(Se)CH2P(Se)Ph2-Se,Se')]BF4
• CAS: 165902-47-6
• 化学式: BF₄*C₃₅H₃₇ClIrP₂Se₂
• 分子量: 992.024
• InChiKey: XDZDPHYAOHVCQL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  四氟化硼(+3)铊(+1) 、 [(η(5)-pentamethylcyclopentadienyl)IrCl(η(2)-Ph2P(Se)CH2P(Se)Ph2-Se,Se')]BF4 、 三甲氧基磷 以 丙酮 为溶剂， 以88%的产率得到[(η(5)-pentamethylcyclopentadienyl)Ir(trimethylphosphite)(η(2)-Ph2P(Se)CH2P(Se)Ph2-Se,Se')](BF4)2
  参考文献：
  名称：

  Pentamethylcyclopentadienyliridium(III) complexes containing tertiary phosphorus chalcogenide ligands: crystal structure of [(η5C5Me5)Ir{PO(OMe)2}{η2(SPPh2)2CH2S, S′}] BF4 · 0.5Me2CO

  摘要：

  Neutral iridium(III) complexes of the unidentate P-donor ligands dppm, dppmS and dppmSe, and cationic complexes with these ligands acting in their bidentate form have been prepared and characterized. Similar cationic complexes with the symmetrical bidentate dichalcogenide ligands dppmS, and dppmSe, have been described. These compounds react with sodium hydride in tetrahydrofuran or with thallium pyrazolate in dichloromethane to yield the new cationic complexes [(eta(5)C(5)Me(5))Ir{eta(3)(EPPh(2))(2)CH-C,E,E'}](+) (E = S, Se) in which the anionic methanide dichalcogenide ligand is acting as a tripod ligand with a C,E,E'-donor set. However, the complexes [(eta(5)C(5)Me(5))IrCl(eta(2)dppmE(2))]BF4 react with P(OMe)(3) in the presence of TIBF4, to give the dicationic compounds [(eta(5)C(5)Me(5))Ir{P(OMe>(3)}(eta(2)dppmE(2))(BF4)(2). In these complexes, the P(OMe)(3) ligand is transformed into a coordinated PO(OMe)(2) group by reaction with sodium iodide in acetone. The structure of the complex [(eta(5)C(5)Me(5))Ir{PO(OMe)(2)}(eta(2)dppmS(2)-S,S')]BF4 . 0.5Me(2)CO have been determined by single crystal X-ray diffraction methods.

  DOI：

  10.1016/0022-328x(95)05909-9
• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 四氟化硼(+3)铊(+1) 、 bis(diphenylselenophopshinyl)methane 以 丙酮 为溶剂， 以76%的产率得到[(η(5)-pentamethylcyclopentadienyl)IrCl(η(2)-Ph2P(Se)CH2P(Se)Ph2-Se,Se')]BF4
  参考文献：
  名称：

  Pentamethylcyclopentadienyliridium(III) complexes containing tertiary phosphorus chalcogenide ligands: crystal structure of [(η5C5Me5)Ir{PO(OMe)2}{η2(SPPh2)2CH2S, S′}] BF4 · 0.5Me2CO

  摘要：

  Neutral iridium(III) complexes of the unidentate P-donor ligands dppm, dppmS and dppmSe, and cationic complexes with these ligands acting in their bidentate form have been prepared and characterized. Similar cationic complexes with the symmetrical bidentate dichalcogenide ligands dppmS, and dppmSe, have been described. These compounds react with sodium hydride in tetrahydrofuran or with thallium pyrazolate in dichloromethane to yield the new cationic complexes [(eta(5)C(5)Me(5))Ir{eta(3)(EPPh(2))(2)CH-C,E,E'}](+) (E = S, Se) in which the anionic methanide dichalcogenide ligand is acting as a tripod ligand with a C,E,E'-donor set. However, the complexes [(eta(5)C(5)Me(5))IrCl(eta(2)dppmE(2))]BF4 react with P(OMe)(3) in the presence of TIBF4, to give the dicationic compounds [(eta(5)C(5)Me(5))Ir{P(OMe>(3)}(eta(2)dppmE(2))(BF4)(2). In these complexes, the P(OMe)(3) ligand is transformed into a coordinated PO(OMe)(2) group by reaction with sodium iodide in acetone. The structure of the complex [(eta(5)C(5)Me(5))Ir{PO(OMe)(2)}(eta(2)dppmS(2)-S,S')]BF4 . 0.5Me(2)CO have been determined by single crystal X-ray diffraction methods.

  DOI：

  10.1016/0022-328x(95)05909-9