Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands
摘要:
Novel molybdenum- and tungsten dinitrogen complexes bearing PNP-type pincer ligands are prepared and characterized by X-ray analysis. Reactions of these molybdenum- and tungsten-dinitrogen complexes with an excess amount of sulfuric acid in THF at room temperature afford ammonia and hydrazine in good yields.