| 20642-09-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• CAS: 20642-09-5
• 化学式: 2Mn*P₂S₆
• 分子量: 364.22
• InChiKey: DGECHCCSUFZTBC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  1.71
• 重原子数：
  9.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  potassium chloride 、 以 水 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and second-order optical nonlinearity of DAMS/Mn2P2S6 intercalated materials by ion exchange method

  摘要：

  Intercalated hybrid materials alternating optical nonlinear organic chromophores and inorganic Mn2P2S6 layers were obtained by ion exchange method. The Mn2P2S6 powder was synthesized by solution-state combined solid-state method, which benefited for MPS3's mass production. The reaction between Mn2P2S6 layers and inserted chromophores was intensified by UV-visible spectroscopy. It was indicated that Mn2P2S6 powders after solution-state combined solid-state method was single crystalline and DAMS molecules self-assembled in the layers of Mn2P2S6 to form J-aggregates. Second-harmonic generation (SHG) of DAMS/Mn2P2S6 thin films was observed by Maker fringe measurement. The DAMS/Mn2P2S6 intercalated material was well formed by ion exchange method. Crown Copyright (C) 2009 Published by Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.cplett.2009.07.019
• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 sodium hypothiophosphate hexahydrate 以 solid 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and second-order optical nonlinearity of DAMS/Mn2P2S6 intercalated materials by ion exchange method

  摘要：

  Intercalated hybrid materials alternating optical nonlinear organic chromophores and inorganic Mn2P2S6 layers were obtained by ion exchange method. The Mn2P2S6 powder was synthesized by solution-state combined solid-state method, which benefited for MPS3's mass production. The reaction between Mn2P2S6 layers and inserted chromophores was intensified by UV-visible spectroscopy. It was indicated that Mn2P2S6 powders after solution-state combined solid-state method was single crystalline and DAMS molecules self-assembled in the layers of Mn2P2S6 to form J-aggregates. Second-harmonic generation (SHG) of DAMS/Mn2P2S6 thin films was observed by Maker fringe measurement. The DAMS/Mn2P2S6 intercalated material was well formed by ion exchange method. Crown Copyright (C) 2009 Published by Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.cplett.2009.07.019

文献信息

• Influence of the Ni^II/Mn^II ratio on the physical properties of heterometallic Ni_2xMn_(2−2x)P₂S₆ phases and potassium intercalates K_0.8Ni_2xMn_(1.6−2x)P₂S₆·2H₂O
  作者：Catalina Cortés、Pablo Fuentealba、Jorge Manzur、Juliana Pérez-Obando、Carolina Aliaga、Nathalie Audebrand、Hector Aguilar-Bolados、Evgenia Spodine

  DOI：10.1039/d0nj04680a

  日期：——

  Conversely, the absorption edge of the solid state UV-visible spectra shifted to lower energies as the percentage of nickel(II) increased, tending to that of the band gap value of the pristine Ni2P2S6 phase. Moreover, the electric conductivity of Ni0.4 was similar to that of the pristine Mn2P2S6 phase, while that of Ni0.8 and Ni1.2 approached the values of the electric conductivity of the pristine

  通过微波辅助法合成了双金属Ni 2 x Mn 2−2 x P 2 S 6相，其中2 X = 0.4（Ni0.4），0.8（Ni0.8）和1.2（Ni1.2）。相应的插层钾K 0.8 Mn 1.6 P 2 S 6 ·2H 2 O，K 0.8 Ni 0.4 Mn 1.2 P 2 S 6 ·2H 2 O和K 0.8 Ni 0.8 Mn 0.8P 2小号6 ·2H 2 O的磁性，光学，和电性能的记录中，为了可视化二次镍的影响（II）上的原始Mn的物理性质的离子2 P 2小号6相。直流磁化率和EPR数据均表明，双金属相层中的反铁磁相互作用减弱，而所有双金属相的临界温度均保持恒定（约80 K），类似于Mn 2 P 2 S 6。。相反，随着镍（II）百分比的增加，固态紫外-可见光谱的吸收边缘转移到较低的能量，趋向于原始Ni 2 P 2 S 6相的带隙值。而且，Ni0.4的电导率与原始Mn 2 P 2 S