[(cyclopentadienyl)2Zr(P(1)(SiMe3)-P(2)(Ph)2)(P(3)(SiMe3)2)] | 1300646-27-8

• 英文名称: [(cyclopentadienyl)2Zr(P(1)(SiMe3)-P(2)(Ph)2)(P(3)(SiMe3)2)]
• 英文别名: [Cp2Zr(P(1)(SiMe3)-P(2)(Ph)2)(P(3)(SiMe3)2)]
• CAS: 1300646-27-8
• 化学式: C₃₁H₄₇P₃Si₃Zr
• 分子量: 688.116
• InChiKey: FPKDRZBRNLTLFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯二茂锆 、 四苯基二膦 、 lithium bis(trimethylsilyl)phosphanide-tetrahydrofuran (1/2) 、 Ph2P-P(SiMe3)Li*3(tetrahydrofuran) 以 正戊烷 为溶剂， 生成 bis{bis(trimethylsilyl)phosphido}zirconocene(IV) 、 [(cyclopentadienyl)2Zr(P(1)(SiMe3)-P(2)(Ph)2)(P(3)(SiMe3)2)]
  参考文献：
  名称：

  General route for the synthesis of terminal phosphanylphosphido complexes of Zr(IV) and Hf(IV): Structural investigations of the first zirconium complex with a phosphanylphosphido ligand

  摘要：

  Reactions of R2P-P(SiMe3)Li with [Cp2MCl2] (M = Zr, Hf) in hydrocarbons yield the related terminal phosphanylphosphido complexes [Cp2M(Cl){(Me3Si)P-PR2-kappa P-1}] (R = Pr-i and Bu-t). The solid state structures of [Cp2M(Cl)(P(SiMe3)-(PPr2)-Pr-i-kappa P-1)] (M = Zr, Hf) were established by single crystal X-ray diffraction studies. The phosphido-P atoms adopt almost planar geometries and the phosphanyl P atoms adopt pyramidal geometries. The reaction of a mixture of (Me3Si)(2)PLi and Ph2P-P(SiMe3)Li with [CpZrCl3] in toluene yields the dinuclear complex [Cp2Zr2Cl5(Ph2PPPSiMe3)(Li THF DME)]. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.031