(η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)] | 640298-73-3

• 英文名称: (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]
• 英文别名: (η5-C5H5)(η5-C5H4C6H3(CH2NMe2)2-3,5)Fe；[(ferrocenyl)C6H3(CH2NMe2)2-2,6]
• CAS: 640298-73-3
• 化学式: C₂₂H₂₈FeN₂
• 分子量: 376.325
• InChiKey: UABQUYLZMASDSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)] 、 dichlorobis(diethyl sulfide)platinum 在 正丁基锂 作用下， 以 not given 为溶剂， 生成 (η5-C5H5)(η5-C5H4C6H2(CH2NMe2)2-2,6-PtCl)Fe
  参考文献：
  名称：

  有机金属π-镊子，NCN钳子和二茂铁在多金属过渡金属配合物的合成中作为分子“ Tinkertoys”

  摘要：

  这篇综述通过分子“ Tinkertoy”方法描述了早晚异二，异三和异四金属过渡金属配合物的合成，反应化学，结构和键合。作为不同金属原子之间的连接单元，可以使用π共轭的富含碳的有机和/或无机基团。还分别给出了这种一维分子线分子，配位聚合物，星形结构和树状取向过渡金属物种的电化学行为。

  DOI：

  10.1021/om058042p
• 作为产物：
  描述：

  ferrocene boronic acid 、 3,5-bis[(dimethylamino)methyl]phenyl iodide 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 sodium hydroxide 作用下， 以 乙二醇二甲醚 为溶剂， 生成 (η5-C5H5)Fe[η5-C5H4(1-C6H3(CH2NMe2)2-3,5)]
  参考文献：
  名称：

  有机金属π-镊子，NCN钳子和二茂铁在多金属过渡金属配合物的合成中作为分子“ Tinkertoys”

  摘要：

  这篇综述通过分子“ Tinkertoy”方法描述了早晚异二，异三和异四金属过渡金属配合物的合成，反应化学，结构和键合。作为不同金属原子之间的连接单元，可以使用π共轭的富含碳的有机和/或无机基团。还分别给出了这种一维分子线分子，配位聚合物，星形结构和树状取向过渡金属物种的电化学行为。

  DOI：

  10.1021/om058042p

文献信息

• Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN=[C6H2(CH2NMe2)2-2,6]−)
  作者：Stefan Köcher、Martin Lutz、Anthony L. Spek、Rajendra Prasad、Gerard P.M. van Klink、Gerard van Koten、Heinrich Lang

  DOI：10.1016/j.ica.2006.05.045

  日期：2006.11

  The meta-diaminoaryl ferrocenes Fc-NCN-H (3) and Fc-C C-NCN-H (5) (Fc = (eta(5)-C5H5)(eta(5)-C5H4)Fe, NCN-H = C6H3(CH2NMe2)(2)-3,5) can be used as precursors in the preparation of heterobimetallic transition metal complexes of structural type Fc-NCN-MX (NCN = [C6H2(CH2NMe2)(2)-2,6](-); MX = PdCl (7), PtCl (8), PtI (9)) and Fc-C C-NCN-MX (MX = PdCl (11), PdI (12), PtCl (13)), respectively. They are accessible by applying different synthesis procedures, including oxidative addition and metallation-transmetallation processes.Cyclovoltammetric studies show that the ferrocene moieties in 3, 5, 7-9 and 11-13 can reversibly be oxidised. The potential of the Fe(II)/Fe(III) redox couple decreases with increasing electron density at the NCN pincer unit. The use of 8 as a possible (electro)chemical sensor in the detection of SO, is discussed as well.The solid-state structures of 8 and 13 are reported. The crystals of 8 contain two molecules of 8 in the asymmetric unit. The plane of the C6H2 moiety is with 27.2(3)degrees and 38.2(3)degrees tilted towards the C5H4 entity, while in 13 an angle of 45.9(3)degrees can be found. The d(8)-electron configured platinum atoms possess a somewhat distorted square-planar surrounding, setup by two Me2NCH2 ortho-substituents, the NCN C-ipso carbon atom and the chloride ligand. (c) 2006 Elsevier B.V. All rights reserved.
• Ferrocene-bridged Pd–NCN pincer complexes
  作者：Stefan Köcher、Gerard P.M van Klink、Gerard van Koten、Heinrich Lang

  DOI：10.1016/s0022-328x(03)00753-8

  日期：2003.11

  The meta-diaminoaryl ferrocene Fe[eta(5)-C5H4(NCNH)](2) [NCNH = 1-C6H3(CH2NMe2)(2)-3,5] (3) can be synthesised by the reaction of Fe[eta(5)-C5H4(ZnCl)](2) (1) with I-C6H3(CH2NMe2)(2)-3,5 (2) in a 1:2 molar ratio in the presence of catalytic amounts of [Pd(PPh3)(2)]. The two meta-dimaminoaryl NCNH pincer units in 3 can be used to assemble multimetallic complexes. Thus, 3 produces on reaction with (BuLi)-Bu-t and (Me2S)(2)PdCl2 trimetallic Fe[eta(5)-C5H4(NCN-4-PdCl)](2) NCN = 1-C6H2(CH2NMe2)(2)-3,5} (6) along with heterobimetallic Fe[eta(5)-C5H4(NCNH)][eta(5)-C5H4(NCN-4-PdCl)] (5). Complex 6 contains two bis-ortho-chelated pincer NCN-PdCl units, whereas 5 possesses one bis-ortho-chelated NCN pincer entity and one non-metallated NCNH moiety. Complex 6 is the first example in organometallic chemistry in which two bis-ortho-chelated diaminoaryl palladium units are bridged via the respective para C-atoms spanned by a redox-active ferrocenyl building block. (C) 2003 Elsevier B.V. All rights reserved.