[(C5H5)Fe(CO)2(η(1)-dppm)]I | 186453-99-6

• 英文名称: [(C5H5)Fe(CO)2(η(1)-dppm)]I
• CAS: 186453-99-6
• 化学式: C₃₂H₂₇FeO₂P₂*I
• 分子量: 688.264
• InChiKey: ZJXIXWXUXBILRM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 [(C5H5)Fe(CO)2(η(1)-dppm)]I 以 四氢呋喃 为溶剂， 以30%的产率得到(C5H5)Fe(μ-CO)2(μ-dppm)RhI2
  参考文献：
  名称：

  Iron-rhodium complexes with a single bridging diphosphine ligand: the crystal structure of [CpFe(μ-CO)2(μ-dppm)RhI2]

  摘要：

  The mononuclear complexes [FeCpI(CO)(2)] 1, [FeCp(CO)(2)(eta(1)-dppm)]I 2, [FeCp(CO)(eta(2)-dppm)]I 3, [FeCp(CO)(2)(eta(1)-dppen)]I 5 and [FeCp(CO)(eta(2)-dppen)]I 6 [dppen = Ph(2)PC(=CH2)PPh(2)] have been synthesised and reacted with [Rh2Cl2(CO)(4)] to produce heterobimetallic complexes of the type [CpFe(mu-CO)(2)(mu-PP)RhX(2)](X = Cl or I). The structure of [CpFe(mu-CO)(2){mu-Ph(2)PCH(2)PPh(2)}RhI2] 4 has been determined by X-ray crystallography.

  DOI：

  10.1016/s0022-328x(96)06525-4
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 、 双二苯基膦甲烷 以 四氢呋喃 为溶剂， 以90%的产率得到[(C5H5)Fe(CO)2(η(1)-dppm)]I
  参考文献：
  名称：

  Iron-rhodium complexes with a single bridging diphosphine ligand: the crystal structure of [CpFe(μ-CO)2(μ-dppm)RhI2]

  摘要：

  The mononuclear complexes [FeCpI(CO)(2)] 1, [FeCp(CO)(2)(eta(1)-dppm)]I 2, [FeCp(CO)(eta(2)-dppm)]I 3, [FeCp(CO)(2)(eta(1)-dppen)]I 5 and [FeCp(CO)(eta(2)-dppen)]I 6 [dppen = Ph(2)PC(=CH2)PPh(2)] have been synthesised and reacted with [Rh2Cl2(CO)(4)] to produce heterobimetallic complexes of the type [CpFe(mu-CO)(2)(mu-PP)RhX(2)](X = Cl or I). The structure of [CpFe(mu-CO)(2){mu-Ph(2)PCH(2)PPh(2)}RhI2] 4 has been determined by X-ray crystallography.

  DOI：

  10.1016/s0022-328x(96)06525-4