(SP-5-13)-氯[[2,2’-[1,2-乙烷二基双[(次氮基-κN)亚甲基]双[4,6-双(1,1-二甲基乙基)苯酚-κO]](2-)]锰 | 172172-24-6

• 中文名称: (SP-5-13)-氯[[2,2’-[1,2-乙烷二基双[(次氮基-κN)亚甲基]双[4,6-双(1,1-二甲基乙基)苯酚-κO]](2-)]锰
• 英文名称: (Sp-5-13)-Chloro[[2,2’-[1,2-Ethanediylbis[(Nitrilo-Κn)Methylidyne]]Bis[4,6-Bis(1,1-Dimethylethyl)Phenolato-Κo]](2-)]Manganese
• 英文别名: 4,4',6,6'-tert-butyl-[2,2'-[ethane-1,2-diil-bis(nitrilo-methylidyne)]diphenolato]-manganese(III)-chloride；{[N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediaminoato(2-)]manganese(III) chloride}；N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylenediaminomanganese(III) chloride；[N,N'-bis-(3,5-di-tert-butylsalicylidene)ethylendiamine]manganese(III) chloride；[N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediaminato(2-)]Mn(III) chloride
• CAS: 172172-24-6
• 化学式: C₃₂H₄₆ClMnN₂O₂
• 分子量: 581.12
• InChiKey: ONODLMNFAFHBJV-GIPDMEFXSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

安全信息

• 危险性防范说明：
  P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313
• 危险性描述：
  H315,H319

反应信息

• 作为反应物：
  描述：

  (SP-5-13)-氯[[2,2’-[1,2-乙烷二基双[(次氮基-κN)亚甲基]双[4,6-双(1,1-二甲基乙基)苯酚-κO]](2-)]锰 、 C₄₀H₃₇O₄P 在 sodium hydroxide 作用下， 以 水 、 丙酮 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  不对称抗衡离子导向的铁催化：高度对映选择性的硫氧化

  摘要：

  由非手性铁（III）-salen阳离子和手性磷酸抗衡离子组成的高活性和对映选择性离子对硫氧化催化剂，可高产率和对映选择性地介导各种硫化物的氧化。观察到的对映选择性，特别是对于贫电子底物，是迄今为止在锰和铁salen体系中的最佳结果。这项工作代表了我们的不对称抗衡阴离子导向催化（ACDC）概念在铁催化中的首次应用。

  DOI：

  10.1002/adsc.201200251
• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 lithium chloride 、 N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine 以 乙醇 为溶剂， 生成 (SP-5-13)-氯[[2,2’-[1,2-乙烷二基双[(次氮基-κN)亚甲基]双[4,6-双(1,1-二甲基乙基)苯酚-κO]](2-)]锰
  参考文献：
  名称：

  将 SALEN 和 SALHD-Mn(III) 配合物包裹在铝柱粘土中用于碳酸氢盐辅助的环己烯催化环氧化

  摘要：

  [Mn(3,5-dtSALEN)Cl] (I) 和 [Mn(3,5-dtSALHD)Cl] (II) 配合物 (3,5-dtSALEN = N,N'-bis(3,5-di-叔丁基水杨醛）乙二胺；3,5-dtSALHD = N'N-双-（3,5-二叔丁基水杨醛）-1,2-环己二胺）通过三种制备方法成功封装在天然膨润土中：（ A) 每种金属配合物直接吸附在先前的铝柱膨润土 Al-PILC 上；(B) 两步液相法：(i) Mn2+ 在 Al-PILC 中的阳离子吸附，通过替代其剩余的阳离子交换容量 (CEC)，然后 (ii) 3,5-dtSALEN 或 3,5- 扩散dtSALHD 配体，用于原位生成相应的层间金属配合物；(C) 将复合物同时支撑/包封在原始起始粘土上。该材料的特点是阳离子交换容量，X 射线衍射、原子吸收、FT-红外和紫外-可见光谱，以及 77 K 下的 N2 吸附。光谱分析证明了配合物在最终材料中的物理封装。方法

  DOI：

  10.1016/j.molcata.2016.01.034
• 作为试剂：
  描述：

  2-氯乙基苯基硫醚 在 (SP-5-13)-氯[[2,2’-[1,2-乙烷二基双[(次氮基-κN)亚甲基]双[4,6-双(1,1-二甲基乙基)苯酚-κO]](2-)]锰 、 双氧水 作用下， 生成 2-氯乙基苯基砜 、 2-氯乙基苯基亚砜
  参考文献：
  名称：

  Locus-Specific Microemulsion Catalysts for Sulfur Mustard (HD) Chemical Warfare Agent Decontamination

  摘要：

  The rates of catalytic oxidative decontamination of the chemical warfare agent (CWA) sulfur mustard (HD, bis(2-chlororethyl) sulfide) and a range (chloroethyl) sulfide simulants of variable lipophilicity have been examined using a hydrogen peroxide-based microemulsion system. SANS (small-angle neutron scattering), SAXS (small-angle X-ray scattering), PGSE-NMR (pulsed-gradient spin-echo NMR), fluorescence quenching, and electrospray mass spectroscopy (ESI-MS) were implemented to examine the distribution of HD, its simulants, and their oxidation/hydrolysis products in a model oil-in-water microemulsion. These measurements not only present a means of interpreting decontamination rates but also a rationale for the design of oxidation catalysts for these toxic materials. Here we show that by localizing manganese-Schiff base catalysts at the oil droplet-water interface or within the droplet core, a range of (chloroethyl) sulfides, including HD, spanning some 7 orders of octanol-water partition coefficient (K-ow), may be oxidized with equal efficacy using dilute (5 wt. % of aqueous phase) hydrogen peroxide as a noncorrosive, environmentally benign oxidant (e.g., t(1/2) (HD) similar to 18 s, (2-chloroethyl phenyl sulfide, C6H5SCH2CH2Cl) similar to 15 s, (thiodiglycol, S(CH2CH2OH)(2)) similar to 19 s {20 degrees C}). Our observations demonstrate that by programming catalyst lipophilicity to colocalize catalyst and substrate, the inherent compartmentalization of the microemulsion can be exploited to achieve enhanced rates of reaction or to exert control over product selectivity. A combination of SANS, ESI-MS and fluorescence quenching measurements indicate that the enhanced catalytic activity is due to the locus of the catalyst and not a result of partial hydrolysis of the substrate.

  DOI：

  10.1021/ja901872y

文献信息

• Influence of additional ligands on the two-phase epoxidation with sodium hypochlorite catalyzed by (salen)managanese(III) complexes
  作者：Jacek Skarżewski、Anil Gupta、Andrzej Vogt

  DOI：10.1016/1381-1169(95)00100-x

  日期：1995.10

  The two-phase epoxidation of olefins with sodium hypochlorite catalyzed by the salen-type Mn(III) complex 1 was examined in the presence of various additional ligands and 4-dodecyloxypyridine 1-oxide (3) was found as the most effective one. The system 1-3 was studied by conductometry and UV-Vis spectra. The results support the hypothesis that the disproportionation of the dimeric mu-oxo Mn(IV) complex producing an active oxidant is strongly favoured by the presence of 3.
• Effect of substituents on the Mn(III)Salen catalyzed oxidation of styrene
  作者：Ágnes Zsigmond、Attila Horváth、Ferenc Notheisz

  DOI：10.1016/s1381-1169(01)00112-1

  日期：2001.6

  dManganese(III)complexes of Salen, Br(2)Salen and (tert-butyl)(4)Salen ligands and their encapsulated analogues were prepared by the intrazeolite ligand synthesis (template synthesis) method. The oxidation of styrene was studied on the above catalysts using molecular oxygen as oxidant and tert-butyl hydroperoxide as initiator. The progress of the reactions was followed both by gas chromatography and by the oxygen consumed. The effect of the substituents on the encapsulation, on the catalytic activity and the effect of the encapsulation on the catalytic activity were studied and discussed. (C) 2001 Elsevier Science B.V. All rights reserved.