bis[(acetato)[μ-bis(salicylidene)-1,3-propanediaminato](dimethylsulfoxide)nickel(II)]nickel(II) | 193757-38-9

• 英文名称: bis[(acetato)[μ-bis(salicylidene)-1,3-propanediaminato](dimethylsulfoxide)nickel(II)]nickel(II)
• CAS: 193757-38-9
• 化学式: C₄₂H₅₀N₄Ni₃O₁₀S₂
• 分子量: 1011.08
• InChiKey: IRMYCEQUTVRFDV-DAMSNTIJSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二亚水杨基-1,3-二氨基丙烷 、 nickel(II) acetate tetrahydrate 、 二甲基亚砜 以 甲醇 、 二甲基亚砜 为溶剂， 生成 bis[(acetato)[μ-bis(salicylidene)-1,3-propanediaminato](dimethylsulfoxide)nickel(II)]nickel(II)
  参考文献：
  名称：

  Bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato](dimethyl sulfoxide)nickel(II)}nickel(II)

  摘要：

  The coordination around the nickel ions in the title complex, [Ni-3(C17H16N2O2)(2)(C2H3O2)(2){(CH3)(2)SO}(2)], is irregular octahedral. The central nickel ion occupying the inversion centre has four O atoms from two N,N'-bis(salicylidene)1,3-propanediaminato (SALPD(2-)) ligands and one O atom from each bridging acetate group. The average Ni-O distance for the central Ni ion is 2.072(2) Angstrom. The coordination around the terminal Ni ions, related by an inversion centre, comprises two O atoms and two N atoms from a SALPD(2-) ligand as well as one O-acetate and one O-DMSO atom. The DMSO and acetate ligands are trans about the terminal Ni atom. The average Ni-O and Ni-N distances for the terminal Ni ions are 2.087 (2) and 2.018 (3) Angstrom, respectively. The Ni ... Ni bridging distance is 3.043 (2) Angstrom.

  DOI：

  10.1107/s0108270197004733