1'-dimethylaminomethyl-1-tri-n-butylstannylruthenocene | 881171-93-3

• 英文名称: 1'-dimethylaminomethyl-1-tri-n-butylstannylruthenocene
• CAS: 881171-93-3
• 化学式: C₂₅H₄₃NRuSn
• 分子量: 577.403
• InChiKey: PDMCODWHUSRUAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 正丁基锂 、 1'-dimethylaminomethyl-1-tri-n-butylstannylruthenocene 以 四氢呋喃 、 正己烷 为溶剂， 生成 1'-dimethylaminomethyl-1-lithiumruthenocenide tetrahydrofuran adduct
  参考文献：
  名称：

  Lithiated dimethylaminomethyl ferrocenes and ruthenocenes

  摘要：

  Dimethylaminomethylferrocenyl lithium and -ruthenocenyl lithium were generated using tin/lithium exchange reactions. The four different metallocenyl lithium compounds were analysed using NMR spectroscopy. The metallocenyl lithium reagents are useful reagents and have been shown to react with MeOD, ClSiMe3 and DMF to give air-stable derivatives. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.034
• 作为产物：
  描述：

  正丁基锂 、 (dimethylaminomethyl)ruthenocene 、 三丁基氯化锡 以 正己烷 、 正戊烷 为溶剂， 以39%的产率得到1'-dimethylaminomethyl-1-tri-n-butylstannylruthenocene
  参考文献：
  名称：

  Lithiated dimethylaminomethyl ferrocenes and ruthenocenes

  摘要：

  Dimethylaminomethylferrocenyl lithium and -ruthenocenyl lithium were generated using tin/lithium exchange reactions. The four different metallocenyl lithium compounds were analysed using NMR spectroscopy. The metallocenyl lithium reagents are useful reagents and have been shown to react with MeOD, ClSiMe3 and DMF to give air-stable derivatives. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.034