[Cu(1-ethylimidazolidine-2-thione-1H)]4 | 869955-61-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻嗪类
• 英文名称: [Cu(1-ethylimidazolidine-2-thione-1H)]4
• 英文别名: [Cu(1-EtImS)]4
• CAS: 869955-61-3
• 化学式: C₂₀H₃₆Cu₄N₈S₄
• 分子量: 771.007
• InChiKey: BDIIYYAYVNUWTE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-乙基咪唑-2-硫酮 、 铜 以 乙腈 为溶剂， 生成 [Cu(1-ethylimidazolidine-2-thione-1H)]4
  参考文献：
  名称：

  Electrochemical synthesis and structural characterization of copper and silver complexes of imidazolidine-2-thione ligands

  摘要：

  The electrochemical oxidation of anodic metal (copper and silver) in acetonitrile solutions of the appropriate 1-R-imidazolidine-2-thione (1-RImSH) afforded complexes of composition [M(1-RImS)], M = Cu, Ag, R = Me, Et, Pr, Tr. The compounds have been characterized by microanalysis, IR, NMR and mass spectroscopy and, in the case of [Cu(1-EtImS)] (1), [Cu(1-PrImS)] (2), [Ag1-PrImS)] (3) and [Ag(1-PrImS)] (4), by X-ray diffraction. Compounds (1) and (2) are tetranuclear with an array of four copper atoms at the vertices of a tetrahedron bridged by four sulfur atoms. Each copper atom has a distorted trigonal [CuS2N] environment with each ligand acting as a mu(2)-N,S(eta(2)-S; eta(1)-N) bidentate S-bridging ligand. Complexes 3 and 4 are hexanuclear with six silver atoms at the vertices of a distorted octahedron and the ligand acting as a mu(2)-N, S(eta(2)-S; eta(1)-N) bidentate S-bridging five-electron donor. In the crystals the copper molecules are interconnected by weak intermolecular C-H... S and C-H... it interactions but, in contrast, the silver molecules are linked by weak intermolecular C-H center dot center dot center dot N and C-H center dot center dot center dot pi interactions. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.06.016