(η5-pentamethylcyclopentadienyl)ruthenium(carbonyl)2(methoxymethyl) | 86853-57-8

• 英文名称: (η5-pentamethylcyclopentadienyl)ruthenium(carbonyl)2(methoxymethyl)
• CAS: 86853-57-8
• 化学式: C₁₄H₂₀O₃Ru
• 分子量: 337.381
• InChiKey: SUPCSHGTIOSADB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η5-pentamethylcyclopentadienyl)ruthenium(carbonyl)2(methoxymethyl) 在 盐酸 作用下， 以 乙醚 、 正戊烷 为溶剂， 以72%的产率得到dicarbonyl(chlormethyl)(η(5)-pentamethylcyclopentadienyl)ruthenium(II)
  参考文献：
  名称：

  Einige beispiele zur reaktivität des dicarbonyl(η5-pentamethylcyclopentadienyl)ruthenium-ions [C5Me5(CO)2Ru]−

  摘要：

  DOI：

  10.1016/0022-328x(84)80347-2
• 作为产物：
  描述：

  K[(η(5)-pentamethylcyclopentadienyl)Ru(CO)2] 以 四氢呋喃 为溶剂， 以67%的产率得到(η5-pentamethylcyclopentadienyl)ruthenium(carbonyl)2(methoxymethyl)
  参考文献：
  名称：

  Einige beispiele zur reaktivität des dicarbonyl(η5-pentamethylcyclopentadienyl)ruthenium-ions [C5Me5(CO)2Ru]−

  摘要：

  DOI：

  10.1016/0022-328x(84)80347-2

文献信息

• Nelson, Gregory O.; Sumner, Charles E., Organometallics, 1986, vol. 5, # 10, p. 1983 - 1990
  作者：Nelson, Gregory O.、Sumner, Charles E.

  DOI：——

  日期：——
• Facile conversion of (η5-C5R5) M(CO)2-halide complexes to halomethyl, alkoxymethyl, and cyanomethyl derivatives (R  H, CH3; M  Fe, Ru; halide  Cl, Br, I)
  作者：John L. Hubbard、William K. McVicar

  DOI：10.1016/0022-328x(92)83185-k

  日期：1992.5

  The CpM(CO)2-X complexes (M = Fe, Ru; X = Cl, Br; CP = eta-5-C5H5, Cp* = eta-5-C5Me5) are completely converted to the corresponding halomethyl derivatives over a 20-30 min period when ethereal diazomethane is added dropwise in the presence of Cu powder. Product work-up involves only simple extraction of the crude product with hexane followed by recrystallization at - 40-degrees-C. Formation of iodomethyl derivatives from iodide precursors requires considerably longer CH2N2 addition times and cannot be completely freed of the starting iodide complexes. Fortunately, iodomethyl complexes can be prepared in 80-95% isolated yield by treating the chloromethyl or bromomethyl derivatives with NaI in acetone/Et2O. The CpFe(CO)2CH2I and Cp*Fe(CO)2CH2I complexes are the most sensitive, decomposing rapidly to polymethylene and the parent iodide complexes upon standing at room temperature. Metathetical reactions of the halomethyl complexes to give alkoxymethyl and cyanomethyl derivatives are described.
• Guerchais, Véronique; Lapinte, Claude; Thépot, Jean-Yves, Organometallics, 1988, vol. 7, # 3, p. 604 - 612
  作者：Guerchais, Véronique、Lapinte, Claude、Thépot, Jean-Yves、Toupet, Loic

  DOI：——

  日期：——
• Nelson, Gregory O., Organometallics, 1983, vol. 2, # 10, p. 1474 - 1475
  作者：Nelson, Gregory O.

  DOI：——

  日期：——
• Thépot, Jean-Yves; Guerchais, Véronique; Toupet, Loic, Organometallics, 1993, vol. 12, # 12, p. 4843 - 4853
  作者：Thépot, Jean-Yves、Guerchais, Véronique、Toupet, Loic、Lapinte, Claude

  DOI：——

  日期：——