1-Methyl-4-(2,2,3,3-tetrafluoro-propoxy)-benzene | 72106-07-1

• 英文名称: 1-Methyl-4-(2,2,3,3-tetrafluoro-propoxy)-benzene
• 英文别名: 1-Methyl-4-(2,2,3,3-tetrafluoropropoxy)benzene
• CAS: 72106-07-1
• 化学式: C₁₀H₁₀F₄O
• 分子量: 222.182
• InChiKey: SPPAMKGUNJCHRV-UHFFFAOYSA-N

物化性质

• 沸点：
  66-67 °C(Press: 2-3 Torr)
• 密度：
  1.2536 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-Methyl-4-(2,2,3,3-tetrafluoro-propoxy)-benzene 、 硝酸 生成 4-(2,2,3,3-tetrafluoropropoxy)benzoic acid
  参考文献：
  名称：

  SHELUDKO E. V.; KALIBABCHUK N. N., ZH. ORGAN. XIMII, 1979, 15, HO 8, 1661-1665

  摘要：

  DOI：
• 作为产物：
  描述：

  对溴甲苯 、 sodium 2,2,3,3-tetrafluoropropan-1-olate 以60%的产率得到
  参考文献：
  名称：

  SHELUDKO E. V.; KALIBABCHUK N. N., ZH. ORGAN. XIMII, 1979, 15, HO 8, 1661-1665

  摘要：

  DOI：

文献信息

• OXIME ESTER
  申请人：Nishimae Yuichi

  公开号：US20130188270A1

  公开（公告）日：2013-07-25

  Compounds of the formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 for example independently of each other are hydro-gen, C 1 -C 20 alkyl, (II), COR 16 or NO 2 , provided that at least one pair of R 1 and R 2 , R 2 and R 3 , R 3 and R 4 , R 5 and R 6 , R 6 and R 7 , or R 7 and R 8 is (III); R 9 , R 10 , R 11 and R 12 for example independently of each other are hydrogen, C 1 -C 20 alkyl which optionally substituted; or R 9 , R 10 , R 11 , and R 12 independently of each other are unsubstituted or substituted phenyl; X is CO or a direct bond; R 13 is for example C 1 -C 20 alkyl which optionally is substituted, C 2 -C 12 alkenyl, C 4 -C 8 cycloalkenyl, C 2 -C 12 alkinyl, C 3 -C 10 -cycloalkyl, phenyl or naphthyl both of which are optionally substituted; R 14 is for example hydrogen, C 3 -C 8 cycloalkyl, C 2 -C 5 alkenyl, C 1 -C 20 alkoxy, C 1 -C 20 alkyl, phenyl or naphthyl; R 15 is for example C 6 -C 20 aryl or C 5 -C 20 heteroaryl; R 16 is for example C 6 -C 20 aryl which is unsubstituted or substituted by one or more C 1 -C 20 alkoxy or C 1 -C 20 alkyl; are in particular suitable as photoinitiators for color filter applications.

  式(I)的化合物，其中R1、R2、R3、R4、R5、R6、R7和R8，例如独立地是氢、C1-C20烷基、(II)、COR16或NO2，条件是至少有一对R1和R2、R2和R3、R3和R4、R5和R6、R6和R7或R7和R8是(III)；R9、R10、R11和R12，例如独立地是氢、C1-C20烷基，可选择地被取代；或者R9、R10、R11和R12独立地是未取代或取代的苯基；X是CO或直接键；R13，例如C1-C20烷基，可选择地被取代，C2-C12烯基，C4-C8环烯基，C2-C12炔基，C3-C10环烷基，苯基或者萘基，两者可选择地被取代；R14，例如氢，C3-C8环烷基，C2-C5烯基，C1-C20烷氧基，C1-C20烷基，苯基或者萘基；R15，例如C6-C20芳基或C5-C20杂芳基；R16，例如C6-C20芳基，未取代或被一个或多个C1-C20烷氧基或C1-C20烷基取代；特别适用于彩色滤光片应用的光引发剂。
• [EN] OXIME ESTER DERIVATIVES OF BENZOCARBAZOLE COMPOUNDS AND THEIR USE AS PHOTOINITIATORS IN PHOTOPOLYMERIZABLE COMPOSITIONS<br/>[FR] DÉRIVÉS ESTER D'OXIME DE BENZOCARBAZOLES ET LEUR UTILISATION COMME PHOTOINITIATEURS DANS DES COMPOSITIONS PHOTOPOLYMÉRISABLES
  申请人：BASF SE

  公开号：WO2012045736A1

  公开（公告）日：2012-04-12

  Compounds of the formula (I), wherein R1, R2, R3, R4, R5, R6, R7 and R8 for example independently of each other are hydro- gen, C1-C20alkyl, (II), COR16 or NO2, provided that at least one pair of R1 and R2, R2 and R3, R3 and R4, R5 and R6, R6 and R7, or R7 and R8 is (III); R9, R10, R11 and R12 for example independently of each other are hydrogen, C1-C20alkyl which optionally substituted; or R9, R10, R11, and R12 independently of each other are unsubstituted or substituted phenyl; X is CO or a direct bond; R13 is for example C1-C20alkyl which optionally is substituted, C2-C12alkenyl, C4- C8cycloalkenyl, C2-C12alkinyl, C3-C10cycloalkyl, phenyl or naphthyl both of which are optionally substituted; R14 is for example hydrogen, C3-C8cycloalkyl, C2-C5alkenyl, C1-C20alkoxy, C1-C20alkyl, phenyl or naphthyl; R15 is for example C6-C20aryl or C5-C20heteroaryl; R16 is for example C6-C20aryl which is unsubstituted or substituted by one or more C1-C20alkoxy or C1-C20alkyl; are in particular suitable as photoinitiators for color filter applications.

  式(I)的化合物，其中R1、R2、R3、R4、R5、R6、R7和R8例如彼此独立地为氢、C1-C20烷基、(II)、COR16或NO2，前提是至少有一对R1和R2、R2和R3、R3和R4、R5和R6、R6和R7或R7和R8为(III)；R9、R10、R11和R12例如彼此独立地为氢、C1-C20烷基，可以选择地取代；或者R9、R10、R11和R12彼此独立地为未取代或取代的苯基；X为CO或直接键；R13例如为C1-C20烷基，可以选择地取代，C2-C12烯基，C4-C8环烯基，C2-C12炔基，C3-C10环烷基，苯基或萘基，两者均可以选择地取代；R14例如为氢、C3-C8环烷基、C2-C5烯基、C1-C20烷氧基、C1-C20烷基、苯基或萘基；R15例如为C6-C20芳基或C5-C20杂芳基；R16例如为未取代或取代的C6-C20芳基，其取代基为一个或多个C1-C20烷氧基或C1-C20烷基；特别适用于彩色滤光片应用的光引发剂。
• Geminal-atom catalysis for cross-coupling
  作者：Xiao Hai、Yang Zheng、Qi Yu、Na Guo、Shibo Xi、Xiaoxu Zhao、Sharon Mitchell、Xiaohua Luo、Victor Tulus、Mu Wang、Xiaoyu Sheng、Longbin Ren、Xiangdong Long、Jing Li、Peng He、Huihui Lin、Yige Cui、Xinnan Peng、Jiwei Shi、Jie Wu、Chun Zhang、Ruqiang Zou、Gonzalo Guillén-Gosálbez、Javier Pérez-Ramírez、Ming Joo Koh、Ye Zhu、Jun Li、Jiong Lu

  DOI：10.1038/s41586-023-06529-z

  日期：2023.10.26

  bonding for diverse C–X (X = C, N, O, S) cross-couplings with a low activation barrier. In situ characterization and quantum-theoretical studies show that such a dynamic process for cross-coupling is triggered by the adsorption of two different reactants at geminal metal sites, rendering homo-coupling unfeasible. These intrinsic advantages of GACs enable the assembly of heterocycles with several coordination

  单原子催化剂 (SAC) 具有明确的活性位点，使其在有机合成中具有潜在意义1,2,3,4。然而，由于空间环境和电子量子态的限制，这些稳定在固体载体上的单核金属物质的结构可能不是催化复杂分子转化的最佳选择5,6。在这里，我们报告了一类异质孪生原子催化剂（GAC），它以特​​定的配位和空间接近度配对单原子位点。在聚合氮化碳 (PCN) 主体中，规则分离的具有离域 π 键合性质的氮锚定基团7允许在高金属密度下以约 4 Å 的基态间隔配位铜孪生位点8。GAC 中各个 Cu 位点的适应性协调，通过动态 Cu-Cu 键合，实现了具有低活化势垒的多种 C-X (X = C、N、O、S) 交叉偶联的协作桥偶联途径。原位表征和量子理论研究表明，这种交叉偶联的动态过程是由两种不同反应物在偕金属位点的吸附引发的，使得同质偶联不可行。GAC 的这些内在优势使得能够组装具有多个配位位点的杂环、空间拥挤的支架和具有高
• SHELUDKO E. V., DOKL. AN USSR, 1980, B, HO 11, 68-70
  作者：SHELUDKO E. V.

  DOI：——

  日期：——
• OXIME ESTER DERIVATIVES OF BENZOCARBAZOLE COMPOUNDS AND THEIR USE AS PHOTOINITIATORS IN PHOTOPOLYMERIZABLE COMPOSITIONS
  申请人：BASF SE

  公开号：EP2625166B1

  公开（公告）日：2014-09-24