10-(3,5-bis(decyloxy)phenyl)-5,5-difluoro-1,3,7,9-tetramethyl-2,8-bis(pyridin-4-ylethynyl)-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium | 1191301-54-8

• 英文名称: 10-(3,5-bis(decyloxy)phenyl)-5,5-difluoro-1,3,7,9-tetramethyl-2,8-bis(pyridin-4-ylethynyl)-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
• CAS: 1191301-54-8
• 化学式: C₅₃H₆₅BF₂N₄O₂
• 分子量: 838.933
• InChiKey: POCIRVIZWVBIIO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  10-(3,5-bis(decyloxy)phenyl)-5,5-difluoro-1,3,7,9-tetramethyl-2,8-bis(pyridin-4-ylethynyl)-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium 、 对二甲氨基苯甲醛 在 哌啶 、 溶剂黄146 作用下， 以 苯 为溶剂， 以48%的产率得到
  参考文献：
  名称：

  Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores

  摘要：

  1,3,5,7-Tetramethyl-Bodipy derivatives undergo Knoevenagel-type condensations with aromatic aldehydes to ultimately yield tetrastyryl-Bodipy derivatives. The resulting dyes absorb and emit strongly in the near IR. As the versatility of the Bodipy dyes are fully appreciated, these new tetrastyryl dyes are likely to be featured in a variety of functional supramolecular systems.

  DOI：

  10.1021/ol9019056
• 作为产物：
  描述：

  4-乙炔基吡啶 、 4,4-difluoro-8-[3',5'-bis(decyloxy)phenyl]-2,6-diiodo-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 二异丙胺 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以75%的产率得到10-(3,5-bis(decyloxy)phenyl)-5,5-difluoro-1,3,7,9-tetramethyl-2,8-bis(pyridin-4-ylethynyl)-5H-5l4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium
  参考文献：
  名称：

  Tetrastyryl-Bodipy Dyes: Convenient Synthesis and Characterization of Elusive Near IR Fluorophores

  摘要：

  1,3,5,7-Tetramethyl-Bodipy derivatives undergo Knoevenagel-type condensations with aromatic aldehydes to ultimately yield tetrastyryl-Bodipy derivatives. The resulting dyes absorb and emit strongly in the near IR. As the versatility of the Bodipy dyes are fully appreciated, these new tetrastyryl dyes are likely to be featured in a variety of functional supramolecular systems.

  DOI：

  10.1021/ol9019056