tris(η(5)-cyclopentadienyl)(μ3-n-decylidyne)trinickel | 163807-46-3

• 英文名称: tris(η(5)-cyclopentadienyl)(μ3-n-decylidyne)trinickel
• CAS: 163807-46-3
• 化学式: C₂₅H₃₄Ni₃
• 分子量: 510.615
• InChiKey: XNNMUXNQFLCJJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  苯基锂 、 正癸烯 、 nickelocene 以 四氢呋喃 为溶剂， 生成 tris(η(5)-cyclopentadienyl)(μ3-n-decylidyne)trinickel
  参考文献：
  名称：

  新型亚烷基炔基三镍团簇的合成

  摘要：

  茂镍发生反应以在苯基末端烯烃的存在下进行形式（三（η 5 -环戊二烯基）（μ 3 -alkylidyne）trinickel簇（NICP）3 CR，它是用于合成一个新的，简单的方法（μ 3 -alkylidyne具有不同R基团的三镍簇。

  DOI：

  10.1016/0022-328x(94)05167-a

文献信息

• The activation of C-H bonds in terminal olefins by cyclopentadienylnickel species
  作者：S. Pasynkiewicz、W. Buchowicz、A. Pietrzykowski、T. Głowiak

  DOI：10.1016/s0022-328x(96)06777-0

  日期：1997.5

  The alkylidynetrinickel clusters (NiCp)(3)C(CH2)(8)CH3 1, (NiCp)(3)CCH3 2 and tetrakis(eta(5)-cyclopentadienyl)dihydrido (NiCp)(4)H-2 3 were isolated from the reaction mixture of nickelocene with phenyllithium in the presence of 1-decene. (NiCp)(3)C(CH2)(4)CH3 and the clusters 2 and 3 were obtained in reaction with 1-hexene. In the presence of 2,4,4-trimethyl-1-pentene, cluster 3 was obtained as the main product of the reaction.In the reaction with 1-decene, organic products (olefins, biphenyl, o-terphenyl, quartephenyl) were identified by GC/MS analyses. The structure of 3 has been determined by X-ray diffraction and characterized by H-1 and C-13 NMR, MS and LR. On the basis of organonickel and organic products formed, the mechanism of the sp(2)-hybridized C-H bond activation by cyclopentadienylnickel species has been discussed. (C) 1997 Elsevier Science S.A.