MoRuCo(CO)8(μ3-S)(η(5)-C5H4C(O)CH3) | 218283-84-2

• 英文名称: MoRuCo(CO)8(μ3-S)(η(5)-C5H4C(O)CH3)
• 英文别名: [η5-C5H4C(O)CH3]RuCoMo(CO)8(μ3-S)；[η5-C5H4COCH3]RuCoMo(CO)8(μ3-S)；(μ3-S)RuCoMo(CO)8(CpC(O)CH3)；SRuCoMo(CO)8[η5-C5H4C(O)Me]
• CAS: 218283-84-2；191278-49-6；218283-85-3
• 化学式: C₁₅H₇CoMoO₉RuS
• 分子量: 619.284
• InChiKey: HNICPOGMWMFJCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  MoRuCo(CO)8(μ3-S)(η(5)-C5H4C(O)CH3) 、 nickelocene 以 四氢呋喃 为溶剂， 以25%的产率得到[η5-C5H4COCH3]RuNi(η5-C5H5)Mo(CO)5(μ3-S)
  参考文献：
  名称：

  含SRuNiM（M = Mo，W）核的手性簇的合成，反应和对映体拆分

  摘要：

  的治疗[（η 5 -C 5 H ^ 4 R）乔鲁姆（CO）8（μ 3 -S）]与NICP 2在THF中在回流温度下使含有官能取代的环戊二烯基6个新颖簇配体[（η 5 -C 5 ħ 5）（η 5 -C 5 H ^ 4 COR）NiRuM（CO）5（μ 3 -S）]（1，M =钼，R = CH 3 ; 2，M = W，R = CH 3 ; 3， M = Mo，R = OC 2 H 5；4M ＝ W，R ＝ OC 2 H 5；m ＝1。5，M ＝ Mo，R ＝ COC 6 H 4 COOCH 3；6 M ＝ W，R ＝ COC 6 H 4 COOCH 3）。群集（的反应1 - 6）与2,4-二硝基苯肼进行了调查。酯基很难水解（簇3 – 6）。酰肼可以很容易地冷凝与酮羰基（簇1和2的环戊二烯基环，以形成复合物上）[（η 5 -C 5 H ^ 5）（η 5-C 5 ħ 4 C（NR）CH 3）NiRuM（CO）5（μ

  DOI：

  10.1016/s0022-328x(02)01989-7
• 作为产物：
  描述：

  nonacarbonyl(μ3-sulfido)dicobaltruthenium(Co-Co,2Ru-Co) 、 sodium acetylcyclopentadiene 、 molybdenum hexacarbonyl 以 四氢呋喃 为溶剂， 以42%的产率得到MoRuCo(CO)8(μ3-S)(η(5)-C5H4C(O)CH3)
  参考文献：
  名称：

  研究的RuCo的反应性2（μ 3 -S）（CO）9：包含四面体芯MRuCoS（MMo，W）和两个四面体芯MRuCoS集群上的集群配合物的合成和表征

  摘要：

  新集群MRuCo（CO）8（μ 3 -S）[ η 5 -C 5 H ^ 4 C（O）CH 3 ]（MMo 2，W 3）和[MRuCo（CO）8（μ 3 -S） ] 2 [ η 5 -C 5 H ^ 4 C（O）C 6 H ^ 4 C（O）C 5 H ^ 4 - η 5 ] [MMo 4，W 5 ]已从的RuCo的反应中分离2（μ 3-S）（CO）9 1与[ η 5 -C 5 H ^ 4 C（O）CH 3（CO）3 M] -（MMo，W）和- [M（CO）3 { η 5 -C 5 ħ 4 C（O）C 6 H ^ 4 C（O）C 5 H ^ 4 - η 5 }（CO）3 M] - [MMo，W]，分别。已经通过单晶X射线衍射方法建立了簇2和5。簇2的晶体是斜方晶系，空间群PBCA，一个= 26.229（7），b = 18.200（3），C ^ = 15.929（4），V = 7604（6）3和Ž

  DOI：

  10.1016/s0022-328x(98)00757-8

文献信息

• Synthesis and reduction of [RuCoMo (μ3-S)(CO)8(RC5H4)] [R  HC(O) (2), CH3C(O) (3), C6H5(O) (4), CH3OC(O)C6H4C(O) (5)] heterometal clusters and structure of [RuCoMo (μ3-S)(CO)8C5H4C(O)C6H4C(O)OCH3]
  作者：Er-Run Ding、Sheng-Min Liu、Zhuan-Yun Zhao、Yuan-Qi Yin、Jie Shun

  DOI：10.1016/s0277-5387(96)00579-7

  日期：1997.1
• Attempts to resolve metal clusters with chiral framework by optically active hydrazides
  作者：Yu-Hua Zhang、Chun-Gu Xia、Yuan-Qi Yin

  DOI：10.1016/s0020-1693(01)00650-8

  日期：2001.12

  Two kinds of optically active hydrazides reacted with three tetrahedron-type clusters, respectively, to form hydrazone cluster diastereoisomers, intending to separate racemic clusters. However, the mixture of diastereoisomers cannot be separated into single diastereoisomer by silica gel chromatography. The H-1 and C-13 NMR spectra established their presence. (C) 2001 Elsevier Science B.V. All rights reserved.
• Synthesis and Characterization of New Mixed‐Metal Tetrahedral Carbonyl Clusters Containing (<i>μ</i> ₃‐E)RuCoM (M=Co, Mo) Core and (−)‐DIOP Diphosphine Ligand
  作者：Bao‐Hua Zhu、Yuan‐Qi Yin

  DOI：10.1080/15533170600651421

  日期：2006.5.1

  Four new mixed-metal tetrahedral clusters [(mu(3)-E)RuCo2(CO)(7) ]((-)-DIOP) (E=Se, 1; S, 2) and [(mu(3)-E)RuCoMo(CO)(7)(CpC(O)CH3)]((-)-DIOP) (E=Se, 3; E=S, 4) were obtained by the reactions of [(mu(3)-E)RuCo2(CO)(9)] (E=Se, S) and [(mu(3)-E)RuCoMo(CO)(8)(CpC(O)CH3)] (E = Se, S) with the diphosphine compound (-)-DIOP [(2,2-dimethyl-1,3-dioxolane-4,5-diylbis-methylene)bisdiphenylphosphine] in n -hexane or THF at room temperature, respectively. All clusters were characterized by C, H element analysis, IR and H-1-NMR spectroscopy. The clusters 1 and 3 also were characterized by P-31-NMR spectroscopy.
• Synthesis and characterization of new RuCoM (M=Co, Mo) mixed-metal linked tetrahedral clusters containing (−)-DIOP and reaction of [(μ3-Se)RuCo2(CO)8]2((−)-DIOP) with Na[Mo(CO)3(η5-C5H4COCH3)]
  作者：Bao-Hua Zhu、Bin Hu、Yuan-Qi Yin、Jie Sun

  DOI：10.1016/j.poly.2005.06.008

  日期：2005.10

  The reactions of diphosphine compound (-)-DIOP [(2,2-dimethyl-1,3-dioxolane-4,5-diylbis-methylene)bisdiphenylphosphine] with [(mu(3)-E)RuCo2(CO)(9)] (E = Se, S) and [(mu(3)-E)RuCoMo(CO)(8)(CpC(O)CH3)] (E = Se, S) in n-hexane and THF at r.t. afford four mixed-metal linked tetrahedral clusters [(mu(3)-E)RuCo2(CO)(8)](2)(-)-DIOP) (E = Se, 1; S, 2) and [(mu(3)-E)RuCoMo(CO)(7)(CPC(O)-CH3)](2)((-)-DIOP) (E = Se, 3; S, 4), respectively. The treatment of 1 with Na[Mo(Co)(3)(eta(5)-C5H4COCH3)] in THF at 60 degrees C produces a known cluster (mu(3)-Se)RuCoMo(CO)(8)(CpC(O)CH3) and a new (-)-DIOP substituted tetrahedral cluster [(mu(3)-Se)RuCoMo(CO)(6)-(CpC(O)CH3)((-)-DIOP)] (5). The structure of cluster I has been determined by single-crystal X-ray diffraction. All clusters were characterized by C, H elemental analysis, IR and H-1 NMR spectroscopy. The clusters 1, 2, 4, 5 also were characterized by P-31 NMR spectroscopy. (c) 2005 Elsevier Ltd. All rights reserved.
• Zhang, Yu-hua; Yuan, Jian-chao; Yin, Yuan-qi, New Journal of Chemistry, 2001, vol. 25, p. 939 - 944
  作者：Zhang, Yu-hua、Yuan, Jian-chao、Yin, Yuan-qi、Zhou, Zhong-yuan、Chan, Albert S. C.

  DOI：——

  日期：——