nonacarbonyl(μ3-sulfido)dicobaltruthenium(Co-Co,2Ru-Co) | 86272-87-9

• 英文名称: nonacarbonyl(μ3-sulfido)dicobaltruthenium(Co-Co,2Ru-Co)
• 英文别名: (μ3-S)RuCo2(CO)9；RuCo2(CO)9(μ-S)
• CAS: 86272-87-9
• 化学式: C₉Co₂O₉RuS
• 分子量: 503.216
• InChiKey: YDSQGYVEAZLPBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  nonacarbonyl(μ3-sulfido)dicobaltruthenium(Co-Co,2Ru-Co) 以 正己烷 、 正戊烷 为溶剂， 生成 octacarbonyl(μ3-sulfido)(trimethylphosphine)dicobaltruthenium(Co-Co,2Ru-Co)
  参考文献：
  名称：

  Bantel, Harald; Bernhardt, Wolfgang; Powell, Anne K., Chemische Berichte, 1988, vol. 121, p. 1247 - 1256

  摘要：

  DOI：
• 作为产物：
  描述：

  在 H₂S 作用下， 以 正己烷 为溶剂， 以16%的产率得到nonacarbonyl(μ3-sulfido)dicobaltruthenium(Co-Co,2Ru-Co)
  参考文献：
  名称：

  Roland, Eckehart; Bernhardt, Wolfgang; Vahrenkamp, Heinrich, Chemische Berichte, 1986, vol. 119, # 8, p. 2566 - 2581

  摘要：

  DOI：

文献信息

• Study on the reactivity of RuCo2(μ3–S)(CO)9: synthesis and characterization of the cluster complexes containing the tetrahedral core MRuCoS (MMo, W) and the two tetrahedral core MRuCoS clusters
  作者：Er-Run Ding、Shu-Lin Wu、Chun-Gu Xia、Yuan-Qi Yin

  DOI：10.1016/s0022-328x(98)00757-8

  日期：1998.10

  New clusters MRuCo(CO)8(μ3-S)[η5-C5H4C(O)CH3] (MMo 2, W 3) and [MRuCo(CO)8(μ3-S)]2[η5-C5H4C(O)C6H4C(O)C5H4-η5][MMo 4, W 5] have been isolated from the reaction of RuCo2(μ3-S)(CO)91 with [η5-C5H4C(O)CH3(CO)3M]− (MMo, W) and −[M(CO)3η5-C5H4C(O)C6H4C(O)C5H4-η5}(CO)3M]− [MMo, W], respectively. Clusters 2 and 5 have been established by single crystal X-ray diffraction methods. The crystals of cluster

  新集群MRuCo（CO）8（μ 3 -S）[ η 5 -C 5 H ^ 4 C（O）CH 3 ]（MMo 2，W 3）和[MRuCo（CO）8（μ 3 -S） ] 2 [ η 5 -C 5 H ^ 4 C（O）C 6 H ^ 4 C（O）C 5 H ^ 4 - η 5 ] [MMo 4，W 5 ]已从的RuCo的反应中分离2（μ 3-S）（CO）9 1与[ η 5 -C 5 H ^ 4 C（O）CH 3（CO）3 M] -（MMo，W）和- [M（CO）3 η 5 -C 5 ħ 4 C（O）C 6 H ^ 4 C（O）C 5 H ^ 4 - η 5 }（CO）3 M] - [MMo，W]，分别。已经通过单晶X射线衍射方法建立了簇2和5。簇2的晶体是斜方晶系，空间群PBCA，一个= 26.229（7），b = 18.200（3），C ^ = 15.929（4），V = 7604（6）3和Ž
• Synthesis and characterization of the novel type of heterometal clusters [(μ3-S)RuCoM(CO)8 CpC(O)]2C6H4 (M = Mo, W) and crystal structure of [(μ3-S)RuCoW(CO)8 CpC(O)]2C6H4
  作者：Er-Run Ding、Yuan-Qi Yin、Jie Sun

  DOI：10.1016/s0277-5387(97)00077-6

  日期：1997.1

  Abstract The reaction of (μ3-S)RuCo2(CO)9 (1) with [NaM(CO)3CpC(O)]2C6H4 [(M = Mo (2), M = W (3)] in refluxing THF gave two new carbonyl clusters, [(μ3-S)RuCoM(CO)8CpC(O)]2C6H6 [M = Mo (4), M = W (5)]. The structure of cluster 5 was established by X-ray diffraction analysis.

  摘要（μ3-S）RuCo2（CO）9（1）与[NaM（CO）3CpC（O）] 2C6H4 [[M = Mo（2），M = W（3）]在回流THF中的反应新的羰基簇，[（μ3-S）RuCoM（CO）8CpC（O）] 2C6H6 [M = Mo（4），M = W（5）]。通过X射线衍射分析建立了簇5的结构。
• Mani, Darjusch; Vahrenkamp, Heinrich, Chemische Berichte, 1986, vol. 119, # 12, p. 3649 - 3671
  作者：Mani, Darjusch、Vahrenkamp, Heinrich

  DOI：——

  日期：——
• Basic cluster reactions. 5. Capping reactions of RuCo2(CO)11
  作者：Eckehart Roland、Heinrich Vahrenkamp

  DOI：10.1021/om50002a021

  日期：1983.8
• Catalytic hydrodesulfurization by supported bimetallic sulfide cluster catalysts
  作者：E.J. Markel、J.W. Van Zee

  DOI：10.1016/0304-5102(92)80086-v

  日期：1992.6

  The synthesis, characterization, and thiophene hydrodesulfurization (HDS) activities of novel organometallic sulfide cluster catalysts are presented. The catalysts are composed of H2SRu3(CO)9, HSRu2Co(CO)9, SRuCo2(CO)9, and [(Co3S2(CO)7]2 supported on carbon and gamma-Al2O3. Although the clusters decompose at industrial HDS temperatures, the catalytic properties of the cluster catalysts at lower temperatures depend on the ratio of ruthenium and cobalt. Temperature-programmed decomposition (TPD) of the supported clusters in flowing hydrogen was monitored using FT-IR and mass spectrometry (MS). Temperatures of decomposition (as determined by the maximum rate of CO evolution) follow the order H2SRu3(CO)9 > HSRu2Co(CO)9 > SRuCo2(CO)9 > [Co3S2(CO)7]2. Significant amounts of H2O are detected as products of cluster decomposition on alumina. TPD/MS data of H2SRu3(CO)9 labeled with (CO)-O-18 indicate that the H2O evolved is mostly formed from the alumina surface and not from cluster-bound carbonyls.Kinetics measurements at 150-degrees-C show that the mixed-metal cluster catalysts are more active for thiophene desulfurization than catalysts containing only one metal component. This trend is reversed at higher temperatures and for catalysts sulfided at 400-degrees-C; that is, the mixed-metal catalysts are less active for thiophene desulfurization than catalysts containing only one metal component. The carbon-supported cluster catalysts are more active for thiophene hydrodesulfurization and more selective for butane formation than catalysts supported on gamma-Al2O3.