tungsten hexachloride*cyclo-octasulfur | 123628-40-0

• 英文名称: tungsten hexachloride*cyclo-octasulfur
• CAS: 123628-40-0
• 化学式: Cl₆W*S₈
• 分子量: 653.096
• InChiKey: GYEUGPWFTIXYRI-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  9.32
• 重原子数：
  15.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  1,2,3,4,5,6,7,8-八硫杂环辛烷 、 六氯化钨 以 二硫化碳 为溶剂， 以59%的产率得到tungsten hexachloride*cyclo-octasulfur
  参考文献：
  名称：

  Baratta, Walter; Calderazzo, Fausto; Daniels, Lee M., Inorganic Chemistry, 1994, vol. 33, # 17, p. 3842 - 3844

  摘要：

  DOI：

文献信息

• Chalcogen Polycations by Oxidation of Elemental Chalcogens with Transition Metal Halides: Synthesis and Crystal Structure of [Se17][WCl6]2
  作者：Johannes Beck、Joerg Wetterau

  DOI：10.1021/ic00128a036

  日期：1995.11

  From WCl6 and selenium Se-17(2+)(WCl6-)(2) is formed in a solid state reaction at 110 degrees C. The structure of the dark red crystals consists of Se-17(2+) polycations built of two seven membered Se rings in the chair confer mation connected by a Se-3 chain, and of distorted octahedral WCl6- anions. The two positive charges of each ion are formally localized on the two triply bound Se atoms. The structure of Se-17(2+) is closely related to that of the previously known S-19(2+).
• Cotton, F. Albert; Kibala, Piotr A.; Sandor, Robert B. W., Acta Crystallographica, Section C: Crystal Structure Communications, 1989, vol. 45, p. 1287 - 1289
  作者：Cotton, F. Albert、Kibala, Piotr A.、Sandor, Robert B. W.

  DOI：——

  日期：——