| 957671-84-0

• CAS: 957671-84-0
• 化学式: C₈H₂₀LiO₄*C₁₈H₃₀B₁₀RhS₃
• 分子量: 740.835
• InChiKey: KDBHLJDYCDSWKP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氢呋喃 、 正丁基锂 、 (1,2-dicarba-closo-dodecaborane(12)-1,2-dithiolate)pentamethylcyclopentadienylrhodium(III) 、 水 、 苯硫酚 以 四氢呋喃 、 乙醚 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Trinuclear Rh₂M Complexes (M = Ni, Pd) Bridged by Butyl Selenolato and Carborane Diselenolato Ligands

  摘要：

  Two new half-sandwich trinuclear Rh2M (M = Ni, Pd) complexes bridged by butyl selenolato and carborane diselenolato ligands, [Cp*Rh{mu-Se2C2(B10H10)}](2)M[mu-Se(C4H9)](2) [M = Ni (4), Pd (5)], have been prepared by the reactions of the [Cp*R{mu-Se2C2(B10H10)}{mu-Se(C4H9)}](-) anion with NiCl2 and Pd(PhCN)(2)Cl-2, respectively. The complexes have been fully characterized by H-1, C-13, and B-11 NMR and IR spectroscopy as well as by element analyses. The molecular structures of 4 and 5 have been determined by single-crystal X-ray diffraction analyses, which show the central MSe4 moiety in a slightly distorted square-planar coordination geometry for M = Ni, Pd. sandwich complexes of the type [Cp*M{E2C2(B10H10)}] (Cp* = eta(5)-C5Me5 M = Co, Rh, Ir; E = S, Se), which can be used for further transformations in a controlled way under various conditions.(8-12) Owing to their rigid backbone, our recent studies have focused on the development of the rational methods to obtain the metal-chalcogenido cores with desired metal and chalcogen compositions. In this paper, we report the synthesis of the [Cp*Rh{mu-Se2C2(B10H10)}{mu-Se(C4H9)}](-) anion as the metallaligand to react with transition metal compounds to afford the half-sandwich mixed-metal trinuclear complexes bridged by selenobutyl-diselenolatocarborane ligands.

  DOI：

  10.1021/om7004035