μ-oxalato(O,O')-bis(pentacarbonylrhenium) | 82338-64-5

• 英文名称: μ-oxalato(O,O')-bis(pentacarbonylrhenium)
• 英文别名: [(Re(CO)5)2(μ, η1:η1-C2O4)]
• CAS: 82338-64-5
• 化学式: C₁₂O₁₄Re₂
• 分子量: 740.538
• InChiKey: YPCWYMOFTONDLP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  μ-oxalato(O,O')-bis(pentacarbonylrhenium) 以 四氢呋喃 为溶剂， 以88%的产率得到[Re2(CO)6(C2O4)]n
  参考文献：
  名称：

  Oxalate-bridged dirhenium(I) hexacarbonyl complexes: synthesis, reactions, and crystal structures

  摘要：

  The complex [{Re(CO)(5)}(2)(mu,eta(1):eta(1)-C2O4)] 1 undergoes thermal decarbonylation to give [Re-2(CO)(6)(C2O4)(n), which reacts with triphenylphosphine and trans-1,2-bis(diphenylphosphino)ethylene (dppene) to give anti-[Re-2(PPh3)(2)(CO)(6)(mu,eta(2):eta(2)-C2O4)] 2 and [Re-2(mu-dppene)(CO)(6)(mu,eta(2) : mu(2) -C2O4)] 4, respectively. Complex 2 is oxidized on prolonged exposure to air (1 week) to form anti-[Re-2(OPPh3)(2)(CO)(6) (mu, eta(2):eta(2) -C2O4)] 3. In the presence of excess dppene, the complex [Re-2(mu-dppene)(2)(CO)(6)(mu, eta(1): eta(1) -C2O4)] 5 is also formed alongside 4. With the chelating diphosphine 1,3-bis(diphenylphosphino)propane (dppp), the complex [(eta(2) -dppp)Re-(CO)(3)( mu, eta(1): eta(1)-C2O4)Re(CO)(3)(eta(2) -dppp)] 6 is formed. The structures of 3 and 4 have been determined by X-ray crystallography. The dppene ligand in complex 4 adopts an unusual "syn" conformation wherein the two phosphorus lone pairs of electrons are eclipsed, thus forming an "A-frame" type of bridge. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.06.017
• 作为产物：
  描述：

  pentacarbonyl(tetrafluoroborato)rhenium 、 oxalic acid dihydrate 以 水 为溶剂， 以65%的产率得到μ-oxalato(O,O')-bis(pentacarbonylrhenium)
  参考文献：
  名称：

  Raab, Klaus; Beck, Wolfgang, Chemische Berichte, 1985, vol. 118, # 9, p. 3830 - 3848

  摘要：

  DOI：

文献信息

• Beck, Wolfgang; Raab, Klaus; Nagel, Ulrich, Angewandte Chemie, 1982, vol. 94, p. 556 - 557
  作者：Beck, Wolfgang、Raab, Klaus、Nagel, Ulrich、Steimann, Manfred

  DOI：——

  日期：——