| 488704-65-0

• CAS: 488704-65-0
• 化学式: CH₄O*C₂₄H₁₈FeN₄O₂*F₆P
• 分子量: 627.286
• InChiKey: XPFQXOBMEHFJPM-MNDNPDPASA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 sodium hexaflorophosphate 、 2-[(2-pyridinylmethylene)amino]phenol 、 三氯化铁 在 2,2'-dimethoxypropane 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Photo-induced spin transition for iron(III) compounds with – interactions

  摘要：

  The magnetic susceptibilities of the spin-crossover compound [Fe(pap)(2)]PF6.MeOH (1) have been measured and compared with that of the previously reported compound [Fe(pap)(2)]ClO4.H2O (2). Compound 1 is a spin-crossover compound with spin transition temperature T-1/2 = 288 K, and does not show a hysteresis loop around the spin transition temperature, in contrast with compound 2. Magnetic susceptibilities measured after illumination prove that 1 exhibits the LIESST effect, so does compound 2. The crystallographic data on the molecular packing show the presence of pi stacking between the aromatic rings of pap ligands, which appears to be responsible for the LIESST effect. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(02)01325-8