Mo(VI)(N-2,4,6-Cl3C6H2)2Cl2(dimethoxyethane) | 339550-49-1

• 英文名称: Mo(VI)(N-2,4,6-Cl3C6H2)2Cl2(dimethoxyethane)
• CAS: 339550-49-1
• 化学式: C₁₆H₁₄Cl₈MoN₂O₂
• 分子量: 645.863
• InChiKey: UGFQLNGDPYTAFQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium molybdate 、 三甲基氯硅烷 、 2,4,6-三氯苯胺 在 triethylamine 作用下， 以 乙二醇二甲醚 为溶剂， 以75%的产率得到Mo(VI)(N-2,4,6-Cl3C6H2)2Cl2(dimethoxyethane)
  参考文献：
  名称：

  Synthesis and structure of a series of new haloaryl imido complexes of molybdenum

  摘要：

  The synthesis of a series of mono- and bis-haloarylimido molybdenum(VI) complexes is described. Two methods of introducing the electron poor imido functionality are employed, first the condensation of substituted anilines with Na2MoO4 in the presence of Me3SiCl/NEt3, secondly the sulfinyl amine metathesis with [Mo(O)(2)Cl-2(dme)] (1). The latter method works even in cases, when the first one does not work. Crystal structures of three complexes [Mo(NC6F5)(O)Cl-2(dme)] (2a), [Mo(N-2,6-Cl2C6H3)(2)Cl-2(dme)] (3b) and[Mo(N-2,4,6-Br3C6H2)(2)Cl-2(dme)] (4) are reported. The unusually small Mo-N-C(Ar) angle of 149.1(5)degrees has been found in the structure of 4. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00605-7