[Cu4(μ-N,N'-bis(salicylidene)-1,3-propylenediamine(2-))2(μ1.1-N3)2(N3)2(H2O)2] | 1202637-63-5

• 英文名称: [Cu4(μ-N,N'-bis(salicylidene)-1,3-propylenediamine(2-))2(μ1.1-N3)2(N3)2(H2O)2]
• CAS: 1202637-63-5
• 化学式: C₃₄H₃₆Cu₄N₁₆O₆
• 分子量: 1018.95
• InChiKey: SWTQCYMAIIIQBI-STGPLLPMSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-二亚水杨基-1,3-二氨基丙烷 、 copper(II) nitrate trihydrate 、 sodium azide 以 甲醇 、 丙酮 为溶剂， 以82%的产率得到[Cu4(μ-N,N'-bis(salicylidene)-1,3-propylenediamine(2-))2(μ1.1-N3)2(N3)2(H2O)2]
  参考文献：
  名称：

  Tetranuclear azido-bridged copper(II) complex [Cu4(μ-salpn)2(μ1,1-N3)2(N3)2(H2O)2]: Synthesis, characterization and crystal structure

  摘要：

  The reaction of salpnH(2) Schiff-base ligand (salpnH(2) = N,N'-bis(salicylidene)-1,3-propylenediamine) with Cu(NO3)(2)center dot 3H(2)O and a large excess of NaN3 (1:2:8 molar ration), lead to the formation of [Cu-4(mu-salPn)(2)(mu(1,1)-N-3)(2)(N-3)(2)(H2O)(2)] (1). which has been successfully obtained and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The strong absorption band at about 2000-2100 cm(-1) and at 1597 cm(-1) regions of the IR spectrum of 1 clearly proves the presence of the both end-on (EO) bridging and terminal azido ions and C=N (azomethine) groups, respectively. Single-crystal X-ray analyses revealed that the copper atoms are bridged alternately by end-to-on (EO) azido and phenoxo-salpn ligands in the prepared tetranuclear copper(II) complex [Cu-4(mu-salpn)(2)(mu(1,1)-N-3)(2)(N-3)(2)(H2O)(2)] (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.068