1-(1-naphthyl)-2-(4-nitrophenyl)-o-carborane | 870009-45-3

• 英文名称: 1-(1-naphthyl)-2-(4-nitrophenyl)-o-carborane
• CAS: 870009-45-3
• 化学式: C₁₈H₂₁B₁₀NO₂
• 分子量: 391.48
• InChiKey: GZPAGFBYEDQVEQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-(1,2-dicarba-closo-dodecaboran-1-yl)naphthalene 、 对氟硝基苯 在 potassium tert-butylate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以90%的产率得到1-(1-naphthyl)-2-(4-nitrophenyl)-o-carborane
  参考文献：
  名称：

  1,2-Dicarba-closo-dodecaboran-1-yl Naphthalene Derivatives

  摘要：

  1,2-Dicarba-closo-dodecaboranes (o-carboranes) and naphthalenes have potential value as components or building blocks for supramolecular systems, We have efficiently synthesized 1-(1,2-dicarba-closo-dodecaboran-1-yl) naphthalene and 2-(1,2-dicarba-closo-dodecaboran-1-yl) naphthalene derivatives by employing three preparative methods: cyclization of the corresponding acetylenes with decaborane(14), an Ullmann-type coupling reaction of carboranes with aryl halide, and the aromatic nucleophilic substitution (SNAr) reaction of aryl-o-carboranes with nitrophenyl halide, The optimum conditions of each method for synthesis of the title compounds were also investigated.

  DOI：

  10.1021/ic0509736