Cd(1,1'-bis(3-carboxy-1-oxopropyl)ferrocene(-1H))2(H2O)4 | 1167428-57-0

• 英文名称: Cd(1,1'-bis(3-carboxy-1-oxopropyl)ferrocene(-1H))2(H2O)4
• 英文别名: Cd(Hbfcs)2(H2O)4
• CAS: 1167428-57-0
• 化学式: C₃₆H₄₂CdFe₂O₁₆
• 分子量: 954.824
• InChiKey: CXGNMPORUVMUCD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  咪唑 、 Cd(1,1'-bis(3-carboxy-1-oxopropyl)ferrocene(-1H))2(H2O)4 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 以56%的产率得到([Cd2(1,1'-bis(3-carboxy-1-oxopropyl)ferrocene(-2H))2(imidazole)6]*4H2O)(n)
  参考文献：
  名称：

  A comparative study of ferrocenyl carboxylate cadmium(II) complexes prepared by two different synthetic methods

  摘要：

  Reaction of ferrocenyl carboxylate H(2)bfcs with Cd(Ac)(2) center dot 2H(2)O (H(2)bfcs = 1,1'-bis(3-carboxy-1-oxopropyl) ferrocene) gives the mononuclear tetrahydrate precursor Cd(Hbfcs)(2)(H2O)(4) (1). Investigation on the substitution reactions of 1 with imidazole or 2,2'-bpy afforded two one-dimensional (1D) complexes {[Cd-2(bfcs)(2)(C3H4N2)(6)] center dot 4H(2)O}(n) (2) and {[Cd(bfcs)(2,2'-bpy)(H2O)] center dot 2H(2)O}(n) (4) (2,2'-bpy = 2,2'-bipyridine), respectively. However, the one-step reactions of H(2)bfcs, Cd(Ac)(2) center dot 2H(2)O with imidazole or 2,2'-bpy result in the formation of two different 1D complexes {[Cd(bfcs)(C3H4N2)(2)] center dot CH3OH center dot 2H(2)O}(n) (3) and [Cd(bfcs)(CH3OH)](n) (5). It can be seen from the results that applying different synthetic routes produce dissimilar complexes from however the same materials and under the same reaction conditions. In addition, investigations of differential pulse voltammetry of these four 1D complexes indicate that their half-wave potentials are slightly higher than that of H(2)bfcs. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.03.018
• 作为产物：
  描述：

  1,1’-bis(3-carboxy-propionyl)-ferrocene 、 水 、 cadmium(II) acetate dihydrate 在 CH₃ONa 作用下， 以 甲醇 、 水 为溶剂， 以32%的产率得到Cd(1,1'-bis(3-carboxy-1-oxopropyl)ferrocene(-1H))2(H2O)4
  参考文献：
  名称：

  A comparative study of ferrocenyl carboxylate cadmium(II) complexes prepared by two different synthetic methods

  摘要：

  Reaction of ferrocenyl carboxylate H(2)bfcs with Cd(Ac)(2) center dot 2H(2)O (H(2)bfcs = 1,1'-bis(3-carboxy-1-oxopropyl) ferrocene) gives the mononuclear tetrahydrate precursor Cd(Hbfcs)(2)(H2O)(4) (1). Investigation on the substitution reactions of 1 with imidazole or 2,2'-bpy afforded two one-dimensional (1D) complexes {[Cd-2(bfcs)(2)(C3H4N2)(6)] center dot 4H(2)O}(n) (2) and {[Cd(bfcs)(2,2'-bpy)(H2O)] center dot 2H(2)O}(n) (4) (2,2'-bpy = 2,2'-bipyridine), respectively. However, the one-step reactions of H(2)bfcs, Cd(Ac)(2) center dot 2H(2)O with imidazole or 2,2'-bpy result in the formation of two different 1D complexes {[Cd(bfcs)(C3H4N2)(2)] center dot CH3OH center dot 2H(2)O}(n) (3) and [Cd(bfcs)(CH3OH)](n) (5). It can be seen from the results that applying different synthetic routes produce dissimilar complexes from however the same materials and under the same reaction conditions. In addition, investigations of differential pulse voltammetry of these four 1D complexes indicate that their half-wave potentials are slightly higher than that of H(2)bfcs. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.03.018