[(C5(CH3)5)IrCl(μ-SSbCl2)2Ir(C5(CH3)5)Cl] | 736148-62-2

• 英文名称: [(C5(CH3)5)IrCl(μ-SSbCl2)2Ir(C5(CH3)5)Cl]
• CAS: 736148-62-2
• 化学式: C₂₀H₃₀Cl₆Ir₂S₂Sb₂
• 分子量: 1175.25
• InChiKey: YLZRQWDQAGHHPI-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(η(5)-C5Me5)IrCl(μ-SH)2Ir(η(5)-C5Me5)Cl] 、 三氯化锑 以 四氢呋喃 为溶剂， 以85%的产率得到[(C5(CH3)5)IrCl(μ-SSbCl2)2Ir(C5(CH3)5)Cl]
  参考文献：
  名称：

  Reactions of hydrosulfido- and hydroselenido-bridged dinuclear Ir, Rh, and Ru complexes with SbCl3 and BiCl3 affording mixed-metal sulfido and selenido clusters containing both noble metals and Group 15 metals

  摘要：

  A new versatile method to synthesize a series of noble metal-Group 15 metal chalcogenido clusters has been found. Thus, treatment of the hydrosulfido- or hydroselenido-bridged dinuclear complexes [Cp*MCl(mu-EH)(2)MCp*Cl] (M = lr, Rh; E = S, Se; Cp* = eta(5)-C5Me5), [CpdegreesRuCl(mu-SH)(2)RuCpdegreesCl] (Cpdegrees= eta(5)-C5EtMe4), and [Ru(L)Cl(mu-SH)(2)Ru(L)Cl] (L = eta(6)-C6Me5H) with M'Cl-3 (M'=Sb, Bi) in THF at room temperature afforded smoothly the clusters [Cp*MCl(mu-EM'Cl-2)(2)MCP*Cl], [CpdegreesRuCl(mu-SM'Cl-2)(2)RuCpdegreesCl], and [Ru(L)Cl(mu-SM'Cl-2)(2)Ru(L)Cl] through dehydrochlorination. The X-ray analyses of eleven new clusters clarified the details of their structures consisting of the cubane-type M2M'2ECl2 cores resulting from the presence of weak MCL...M' bonding interactions in addition to the normal M-E, M-Cl, and M'-E bonds. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.04.022