1,1'-bis[((6-propionylaminopyrid-2-yl)amino)carbonyl]ferrocene | 671802-30-5

• 英文名称: 1,1'-bis[((6-propionylaminopyrid-2-yl)amino)carbonyl]ferrocene
• CAS: 671802-30-5
• 化学式: C₂₈H₂₈FeN₆O₄
• 分子量: 568.415
• InChiKey: BLTRWBUWVWISTI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5,5-二乙基丙二酰脲 、 1,1'-bis[((6-propionylaminopyrid-2-yl)amino)carbonyl]ferrocene 以 氘代氯仿 为溶剂， 生成 1,1'-bis[((6-propionylaminopyrid-2-yl)amino)carbonyl]ferrocene * barbiral 1:1 complex
  参考文献：
  名称：

  Binding and Electrochemical Recognition of Barbiturate and Urea Derivatives by a Regioisomeric Series of Hydrogen-Bonding Ferrocene Receptors

  摘要：

  A series of ferrocene-containing amidopyridyl receptors, in two regioisomeric forms (1,1' and 1,3), have been shown to bind cyclic organic molecules in chloroform through complementary hydrogen-bonding interactions. Complexation was monitored by NMR spectroscopy and by cyclic voltammetry. The magnitude of the host-guest binding strength and the redox response to complexation depend on both the type and the relative position of the amidopyridyl groups on the cyclopentadienyl rings of the ferrocene.

  DOI：

  10.1021/om034217o
• 作为产物：
  描述：

  bis(6-aminopyridin-2-yl)-1,1'-ferrocenedicarboxylic amide 、 丙酰氯 在 triethylamine 作用下， 以 四氢呋喃 为溶剂， 以46%的产率得到1,1'-bis[((6-propionylaminopyrid-2-yl)amino)carbonyl]ferrocene
  参考文献：
  名称：

  Binding and Electrochemical Recognition of Barbiturate and Urea Derivatives by a Regioisomeric Series of Hydrogen-Bonding Ferrocene Receptors

  摘要：

  A series of ferrocene-containing amidopyridyl receptors, in two regioisomeric forms (1,1' and 1,3), have been shown to bind cyclic organic molecules in chloroform through complementary hydrogen-bonding interactions. Complexation was monitored by NMR spectroscopy and by cyclic voltammetry. The magnitude of the host-guest binding strength and the redox response to complexation depend on both the type and the relative position of the amidopyridyl groups on the cyclopentadienyl rings of the ferrocene.

  DOI：

  10.1021/om034217o