| 1500106-36-4

• CAS: 1500106-36-4
• 化学式: C₉₉H₆₃BF₂N₅O₆P₃
• 分子量: 1560.35
• InChiKey: KETLPNUUMGJTMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 对二甲氨基苯甲醛 在 哌啶 、 magnesium(II) perchlorate 、 溶剂黄146 作用下， 以 甲苯 为溶剂， 以21%的产率得到
  参考文献：
  名称：

  Highly efficient energy transfer in BODIPY–pyrene decorated cyclotriphosphazene

  摘要：

  In this study, two different cyclophosphazene compounds bearing five pyrene units and one borondipyrromethene unit were designed and synthesized. All compounds were fully characterized by elemental analysis, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, H-1, C-13 and P-31 NMR spectroscopy. The photophysical properties of the new compounds were investigated by means of absorption and fluorescence spectroscopies in dilute dichloromethane solutions. Both systems exhibit a highly efficient energy transfer process, from the excited pyrene units to the borondipyrromethene units. The photophysical studies indicated that the compounds exhibit large Stokes' shifts unlike reference simple BODIPY dyes. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.07.022
• 作为产物：
  描述：

  2,4-二甲基吡咯 、 三氟化硼乙醚 、 1,1,3,3,5-pentahydroxypyrene -5-(4-formylphenoxy)cyclotriphosphazatriene 在 三氟乙酸 、 2,3-二氯-5,6-二氰基-1,4-苯醌 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以22%的产率得到
  参考文献：
  名称：

  Highly efficient energy transfer in BODIPY–pyrene decorated cyclotriphosphazene

  摘要：

  In this study, two different cyclophosphazene compounds bearing five pyrene units and one borondipyrromethene unit were designed and synthesized. All compounds were fully characterized by elemental analysis, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, H-1, C-13 and P-31 NMR spectroscopy. The photophysical properties of the new compounds were investigated by means of absorption and fluorescence spectroscopies in dilute dichloromethane solutions. Both systems exhibit a highly efficient energy transfer process, from the excited pyrene units to the borondipyrromethene units. The photophysical studies indicated that the compounds exhibit large Stokes' shifts unlike reference simple BODIPY dyes. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2013.07.022