[(n-BuIn(2-pyridyl)3)Li*THF] | 888945-66-2

• 英文名称: [(n-BuIn(2-pyridyl)3)Li*THF]
• CAS: 888945-66-2
• 化学式: C₂₃H₂₉InLiN₃O
• 分子量: 485.264
• InChiKey: JNMHZMMZHSUCJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(n-BuIn(2-pyridyl)3)Li*THF] 在 FeBr₂ 作用下， 以 not given 为溶剂， 生成 indium
  参考文献：
  名称：

  Syntheses and Structure of Heterometallic Complexes Containing Tripodal Group 13 Ligands [RE(2-py)₃]^- (E = Al, In)

  摘要：

  Reactions of the Al(III) complex [{MeAl(2-py)(3)}Li center dot THF] (1), containing the tripodal [MeAl(2-py)(3)](-) ligand, with [(C7H8)Mo(CO)(3)], CaI2, and ZnCl2 give the trimetallic and bimetallic complexes [{MeAl(2-py)(3)}Mo(CO)(3)Li(THF)(3)] (2), [{MeAl(2-py)(3)}(2)Ca] (3), and [{MeAl(2-py)(3)}ZnCl] (4), respectively. [{(n)-BuIn(2-py)(3)}Li center dot THF] (5), an In-III analogue of 1 containing the [(BuIn)-Bu-n(2-py)(3)](-) anion, is obtained by the one-pot reaction of (BuLi)-Bu-n with InCl3 followed by reaction with 2-Li-py. Complex 5 reacts with [(C7H8)Mo(CO)(3)] to give [{(BuIn)-Bu-n(2-py)(3)}Mo(CO)(3)Li(THF)(2)](infinity) (6) (analogous to the Al-III complex 2). The X-ray structures of the new complexes 2, 3, 4, 5, and 6 are reported.

  DOI：

  10.1021/om0600691
• 作为产物：
  描述：

  2-吡啶基锂 、 正丁基锂 、 氯化铟 以 四氢呋喃 、 正己烷 为溶剂， 以13%的产率得到[(n-BuIn(2-pyridyl)3)Li*THF]
  参考文献：
  名称：

  Syntheses and Structure of Heterometallic Complexes Containing Tripodal Group 13 Ligands [RE(2-py)₃]^- (E = Al, In)

  摘要：

  Reactions of the Al(III) complex [{MeAl(2-py)(3)}Li center dot THF] (1), containing the tripodal [MeAl(2-py)(3)](-) ligand, with [(C7H8)Mo(CO)(3)], CaI2, and ZnCl2 give the trimetallic and bimetallic complexes [{MeAl(2-py)(3)}Mo(CO)(3)Li(THF)(3)] (2), [{MeAl(2-py)(3)}(2)Ca] (3), and [{MeAl(2-py)(3)}ZnCl] (4), respectively. [{(n)-BuIn(2-py)(3)}Li center dot THF] (5), an In-III analogue of 1 containing the [(BuIn)-Bu-n(2-py)(3)](-) anion, is obtained by the one-pot reaction of (BuLi)-Bu-n with InCl3 followed by reaction with 2-Li-py. Complex 5 reacts with [(C7H8)Mo(CO)(3)] to give [{(BuIn)-Bu-n(2-py)(3)}Mo(CO)(3)Li(THF)(2)](infinity) (6) (analogous to the Al-III complex 2). The X-ray structures of the new complexes 2, 3, 4, 5, and 6 are reported.

  DOI：

  10.1021/om0600691