| 1443551-52-7

• CAS: 1443551-52-7
• 化学式: C₁₂H₁₆N₃Ru*F₆P
• 分子量: 448.313
• InChiKey: LPUMRUJVSDJCAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 cyclopentadienylthallium(I) 以 四氢呋喃 为溶剂， 以67%的产率得到[(η-cyclopentadienyl)(η-benzene)ruthenium] hexafluorophosphate
  参考文献：
  名称：

  Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands

  摘要：

  The UV irradiation of [(eta(5)-C6H7)Ru(C6H6)](+) in MeCN gives the title complex, in which acetonitrile ligands are readily replaced by cyclopentadienide and tricarbollide anions; the structure of the tricarbollide derivative 1-(eta(5)-C6H7)-12-(BuNH)-N-t-1,2,4,12-RuC3B8H10 was established by X-ray diffraction analysis.

  DOI：

  10.1016/j.mencom.2013.05.003
• 作为产物：
  描述：

  {Ru(η-C6H6)(η5-C6H7)}PF6 、 乙腈 反应 4.0h， 以75%的产率得到
  参考文献：
  名称：

  Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands

  摘要：

  The UV irradiation of [(eta(5)-C6H7)Ru(C6H6)](+) in MeCN gives the title complex, in which acetonitrile ligands are readily replaced by cyclopentadienide and tricarbollide anions; the structure of the tricarbollide derivative 1-(eta(5)-C6H7)-12-(BuNH)-N-t-1,2,4,12-RuC3B8H10 was established by X-ray diffraction analysis.

  DOI：

  10.1016/j.mencom.2013.05.003