monocarbonyltris(trimethylphosphine)nickel | 15376-84-8

• 英文名称: monocarbonyltris(trimethylphosphine)nickel
• 英文别名: [nickel(0)(carbonyl)(trimethylphosphine)3]
• CAS: 15376-84-8
• 化学式: C₁₀H₂₇NiOP₃
• 分子量: 314.935
• InChiKey: QVDTYFWBDFRPMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  monocarbonyltris(trimethylphosphine)nickel 、 ethene tris(trimethylphospine)cobalt 以 甲苯 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Triangulo cluster molecules of cobalt(0) and nickel(0) containing trimethylphosphine and carbonyl ligands: syntheses, properties, and x-ray structures

  摘要：

  Trinuclear clusters HCo3(mu-CO)a(PMe3)6 (1) and Co2Ni(mu-CO)3(PMe3)6 (2) are syn in high yields from mononuclear precursors by thermal or photochemical activation. X ray structural data of 1 and 2 show molecular cores of regular M3 triangles. 1: trigonal, space group R3cBAR, a = 10.685 (2) angstrom, c = 52.496 (10) angstrom, and Z = 6. 2: trigonal, space group R3cBAR, a = 10.689 (1) angstrom, c = 52.778 (7) angstrom, and Z = 6. While the hydrogen atom of 1 was not located, a positional disorder of metal atoms in 2 gives rise to D3h symmetry Of the M3(CO)3P6 skeleton in both structures. Calculations of the INDO/1 type support proposals of chemical bonding in 1 and 2.

  DOI：

  10.1021/om00044a035
• 作为产物：
  描述：

  三甲基膦 、 tetracarbonyl nickel 以 neat (no solvent) 为溶剂， 生成 monocarbonyltris(trimethylphosphine)nickel
  参考文献：
  名称：

  Bigorgne, M., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1960, vol. 250, p. 3484 - 3486

  摘要：

  DOI：

文献信息

• Nickel–heterocumulene complexes stabilized by trimethylphosphine: Synthesis, characterization and catalytic application in organozinc coupling with CS2
  作者：Ning Huang、Xiaoyan Li、Wengang Xu、Hongjian Sun

  DOI：10.1016/j.ica.2012.09.002

  日期：2013.1

  The reactivity of Ni(PMe3)(4) with CO2, CS2 and SCNPh was studied. Although CO2 is structurally homologous compound with CS2 and SCNPh, its reactivity with Ni(PMe3)(4) shows a different result with those of CS2 and SCNPh. Reactions of Ni(PMe3)(4) with carbon disulfide and phenyl isothiocyanate in THF give the tetrahedral coordinate complexes (Me3P)(3)Ni(eta(2)-CS2) (1) and (Me3P)(3)Ni(eta(2)-SCNPh) (3), characterized by standard spectroscopic methods and X-ray diffraction. Nickel(0) complexes 1 and 3 are stabilized by the strong donor ligand PMe3. In the case of CO2, attempts to isolate the expected nickel(0) complex (Me3P)(3)Ni(eta(2)-CO2) (4) proved to be unsuccessful. To further extend the utility of our nickel catalysts, the catalytic coupling of organozinc bearing different functionalities with CS2 was explored. With 10 mol% of 1 as the catalyst, MeZnMe, EtZnEt and PhZnBr coupled with CS2 to form the corresponding methyl dithiocarboxylate following esterfication of the initial products. (C) 2012 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: Org.Verb.1, 1.1.1.1.1, page 10 - 26
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• Bigorgne, M.; Zelwer, A., Bulletin de la Societe Chimique de France
  作者：Bigorgne, M.、Zelwer, A.

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• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.B3, 18, page 803 - 805
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• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.B3, 24, page 817 - 820
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