Boroxine: A novel approach to the phosphorus trifluoride-borane system
作者:Lawrence Barton
DOI:10.1016/0022-1902(68)80339-2
日期:1968.8
The gas phase reaction between boroxine and phosphorus trifluoride has been studied and shown to proceed as: B3O3H3(g) + PF3(g) → BH3PF3(g) + B2O3(s). Rate date obtained using an i.r. absorbance technique show a first order dependence on boroxine.