germanium monochloride | 14929-46-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 类金属盐
• 英文名称: germanium monochloride
• 英文别名: germanium fluoride；Germanium-fluorine；fluorogermanium
• CAS: 14929-46-5
• 化学式: FGe
• 分子量: 91.5884
• InChiKey: HHFCFXJTAZTLAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.04
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  锗烷 、 fluorine 以 gas 为溶剂， 生成 germanium monochloride
  参考文献：
  名称：

  Chemiluminescent reactions of ground and metastable states of the group IV A elements with halogens

  摘要：

  Earlier work on chemiluminescent beam-gas reactions of the ground states (3 PJ ) of Si, Ge, and Sn with F2 and of both ground and metastable states (1 D, 1 S) of Sn with Cl2 , Br2, and I2 is extended to include reactions of both ground and metastable states of Si, Ge, and Sn with F2 , Cl2 , Br2 , I2 , and ICl. Chemiluminescent products of metal halides and/or dihalides were observed in all of these reactions, although attempts to observe that in the similar reactions of Pb were unsuccessful. In ICl reactions with Si, Ge, and Sn, both monochloride and dichloride emission occurs, confirming the previously proposed mechanism for creating dihalide emission in Sn reactions with Br2 and I2 via a monohalide intermediate.

  DOI：

  10.1063/1.456952

文献信息

• Chemiluminescent reactions of ground and metastable states of the group IV A elements with halogens
  作者：J. H. Wang、B. S. Cheong、J. M. Parson

  DOI：10.1063/1.456952

  日期：1989.9

  Earlier work on chemiluminescent beam-gas reactions of the ground states (3 PJ ) of Si, Ge, and Sn with F2 and of both ground and metastable states (1 D, 1 S) of Sn with Cl2 , Br2, and I2 is extended to include reactions of both ground and metastable states of Si, Ge, and Sn with F2 , Cl2 , Br2 , I2 , and ICl. Chemiluminescent products of metal halides and/or dihalides were observed in all of these reactions, although attempts to observe that in the similar reactions of Pb were unsuccessful. In ICl reactions with Si, Ge, and Sn, both monochloride and dichloride emission occurs, confirming the previously proposed mechanism for creating dihalide emission in Sn reactions with Br2 and I2 via a monohalide intermediate.